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Abstract <p>Donor-acceptor complexes of the Ga[N(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>]<sub>3</sub> Lewis acid with pyridine and diethyl ether are prepared for the first time and characterized by single-crystal XRD. The gallium atom in the complexes has a trigonal-pyramidal environment with bond angles significantly differing from the tetrahedral ones, indicating a hindered character of the transformation of the Lewis acid from the free state to the geometry of the donor-acceptor complex.</p>

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Donor-Acceptor Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Pyridine and Diethyl Ether

  • 期刊论文

  • 发表日期：

    2025年2月1日

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  • A. S. Zavgorodnii,
  • M. A. Kryukova,
  • A. Y. Timoshkin

摘要

Abstract

Donor-acceptor complexes of the Ga[N(C6F5)2]3 Lewis acid with pyridine and diethyl ether are prepared for the first time and characterized by single-crystal XRD. The gallium atom in the complexes has a trigonal-pyramidal environment with bond angles significantly differing from the tetrahedral ones, indicating a hindered character of the transformation of the Lewis acid from the free state to the geometry of the donor-acceptor complex.