<p>The halide perovskite CsPbBr<sub>3</sub> demonstrates great potential for use in various optoelectronic devices due to its exceptional photoelectric properties. However, electron mobility in these crystals remains insufficiently high. Experimental studies of the crystal structure and electronic properties of CsPb(Br<sub>1 –</sub> <sub><i>x</i></sub>Cl<sub><i>x</i></sub>)<sub>3</sub> single crystals have allowed for the determination of an optimal impurity chlorine ion content (<InlineEquation ID="IEq1"> <EquationSource Format="TEX">\(x \approx 0.07\)</EquationSource> <!--JETPLet2561018Simonenko-m1--> </InlineEquation>), which significantly increases electron mobility to a value of 215.2 cm<sup>2</sup> V<sup>–1</sup> s<sup>–1</sup>.</p>

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On the Effects of Chlorine Doping in CsPbBr3 Single Crystals

  • I. O. Simonenko,
  • I. R. Sayarov,
  • A. R. Tameev,
  • Ya. B. Martynov,
  • R. G. Nazmitdinov

摘要

The halide perovskite CsPbBr3 demonstrates great potential for use in various optoelectronic devices due to its exceptional photoelectric properties. However, electron mobility in these crystals remains insufficiently high. Experimental studies of the crystal structure and electronic properties of CsPb(Br1 – xClx)3 single crystals have allowed for the determination of an optimal impurity chlorine ion content ( \(x \approx 0.07\) ), which significantly increases electron mobility to a value of 215.2 cm2 V–1 s–1.