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Abstract <p>The kinetics of radiation-induced telomerization of tetrafluoroethylene in dimethyl carbonate and dimethoxyethane was studied, and new telomers of tetrafluoroethylene were obtained. A detailed study of IR spectra confirmed the fact of inclusion of fragments of solvent molecules in the composition of the resulting telomers. Selection of synthesis parameters (tetrafluoroethylene concentration and radiation dose) made it possible to obtain telomer solutions with characteristics required for their further use as an additive to electrolytes for lithium-ion batteries.</p>

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Radiation-Chemical Synthesis of Tetrafluoroethylene Telomers in Dimethyl Carbonate and Dimethoxyethane

  • 期刊论文

  • 发表日期：

    2025年8月6日

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  • G. A. Kichigina,
  • P. P. Kushch,
  • G. R. Baimuratova,
  • N. A. Slesarenko,
  • O. A. Kraevaya,
  • O. V. Yarmolenko,
  • D. P. Kiryukhin

摘要

Abstract

The kinetics of radiation-induced telomerization of tetrafluoroethylene in dimethyl carbonate and dimethoxyethane was studied, and new telomers of tetrafluoroethylene were obtained. A detailed study of IR spectra confirmed the fact of inclusion of fragments of solvent molecules in the composition of the resulting telomers. Selection of synthesis parameters (tetrafluoroethylene concentration and radiation dose) made it possible to obtain telomer solutions with characteristics required for their further use as an additive to electrolytes for lithium-ion batteries.