<p>We report the discovery of a (Al,Cu)-bearing micrometeorite recovered at the top of Mt. Gariglione (Italy). The micrometeorite exhibits a highly vesicular scoriaceous structure characterized by broadly chondritic silicate-dominated composition (S-type) with relict phenocrystals of forsteritic olivine dispersed in a Ca-rich silicate glass with pyroxene composition, droplets of FeNi metal, oxides and sporadic Ni-rich sulphides embedded in a magnetite rim. The oxygen 3-isotope analyses give values close to the slope ~1 CCAM. A reduced assemblage of (Al,Cu)-alloys partially fills the open voids of the micrometeorite and shows variable compositions: from almost pure Cu up to Al-dominated phases with a predominance of khatyrkite, stolperite and unnamed Cu<sub>3</sub>Al<sub>2</sub>. Locally, small grains (about 1-2 µm in size) embedded in stolperite show a Fe-Si enrichment and are characterized by a long-range ordering resembling a quasicrystalline structure. This finding represents a unique natural quasicrystal approximant with composition Al<sub>52</sub>Cu<sub>31</sub>Fe<sub>10</sub>Si<sub>7</sub>.</p>

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Unique (Al,Cu)-alloys discovered in a micrometeorite from Southern Italy

  • Giovanna Agrosì,
  • Paola Manzari,
  • Daniela Mele,
  • Gioacchino Tempesta,
  • Floriana Rizzo,
  • Tiziano Catelani,
  • Guangming Cheng,
  • Nan Yao,
  • Johan Villeneuve,
  • Luca Bindi

摘要

We report the discovery of a (Al,Cu)-bearing micrometeorite recovered at the top of Mt. Gariglione (Italy). The micrometeorite exhibits a highly vesicular scoriaceous structure characterized by broadly chondritic silicate-dominated composition (S-type) with relict phenocrystals of forsteritic olivine dispersed in a Ca-rich silicate glass with pyroxene composition, droplets of FeNi metal, oxides and sporadic Ni-rich sulphides embedded in a magnetite rim. The oxygen 3-isotope analyses give values close to the slope ~1 CCAM. A reduced assemblage of (Al,Cu)-alloys partially fills the open voids of the micrometeorite and shows variable compositions: from almost pure Cu up to Al-dominated phases with a predominance of khatyrkite, stolperite and unnamed Cu3Al2. Locally, small grains (about 1-2 µm in size) embedded in stolperite show a Fe-Si enrichment and are characterized by a long-range ordering resembling a quasicrystalline structure. This finding represents a unique natural quasicrystal approximant with composition Al52Cu31Fe10Si7.