<p>Organic room-temperature phosphorescence (RTP) has shown potential applications in the fields of biomedical imaging, chemical sensing, anti-counterfeiting, and encryption. Inspired by natural photosynthesis, artificial light-harvesting systems based on the phosphorescence-type energy transfer (ET) from the triplet excited states of organic RTP emitters have emerged as promising candidates to expand organic afterglow materials and promote practical applications. This review presents a fundamental understanding of phosphorescence-type ET processes, including the one-step triplet-to-singlet ET, stepwise triplet-to-singlet-to-singlet ET, and triplet-to-triplet ET. We highlight significant advances in the design, modulation, and application of phosphorescence-type ET systems and provide an outlook on application prospects and challenges.</p><p></p>

错误:搜索内容不能为空,请输入英文关键词
错误:关键词超出字数限制,请精简
高级检索

Recent progress in triplet energy transfer systems toward organic afterglow materials

  • Kaiwen Wu,
  • Dan Liu,
  • Lixun Zhu,
  • Tianhao Wu,
  • Yanning Xu,
  • Chenghan He,
  • Yu Xiong,
  • Zheng Zhao,
  • Ben Zhong Tang

摘要

Organic room-temperature phosphorescence (RTP) has shown potential applications in the fields of biomedical imaging, chemical sensing, anti-counterfeiting, and encryption. Inspired by natural photosynthesis, artificial light-harvesting systems based on the phosphorescence-type energy transfer (ET) from the triplet excited states of organic RTP emitters have emerged as promising candidates to expand organic afterglow materials and promote practical applications. This review presents a fundamental understanding of phosphorescence-type ET processes, including the one-step triplet-to-singlet ET, stepwise triplet-to-singlet-to-singlet ET, and triplet-to-triplet ET. We highlight significant advances in the design, modulation, and application of phosphorescence-type ET systems and provide an outlook on application prospects and challenges.