<p>Bloch surface waves (BSWs), generated at the interface of a truncated one-dimensional photonic crystal (1DPhC) and the adjacent medium (analyte), are accompanied by narrow resonance dips that are very advantageous compared to too wide resonance dips associated with the surface plasmon resonance (SPR) phenomenon. Consequently, BSW-based sensors have been thoroughly studied and applied in the field of optical sensors, but their sensitivity to gaseous analytes does not outperform the sensitivity of the SPR-based sensors. One of the possible solutions to enhance the sensitivity represents a metal-dielectric 1DPhC. We report on a sensing concept for gaseous analytes based on the wavelength interrogation and resonances supported by a metal-dielectric 1DPhC in the Kretschmann configuration. For a metal-dielectric 1DPhC comprising bilayers of TiO<InlineEquation ID="IEq1"> <EquationSource Format="TEX">\(_2\)</EquationSource> </InlineEquation>/Au with a termination layer of TiO<InlineEquation ID="IEq2"> <EquationSource Format="TEX">\(_2\)</EquationSource> </InlineEquation>, we show that the Bloch-like SW-based resonances are resolved for both TE and TM waves. For the TE wave and the refractive index (RI) in a range of 1–1.0015, a sensitivity of 10,900 nm/RIU, a figure of merit (FOM) of 474 RIU<InlineEquation ID="IEq3"> <EquationSource Format="TEX">\(^{-1}\)</EquationSource> </InlineEquation>, and a limit of detection (LOD) of 9.3 <InlineEquation ID="IEq4"> <EquationSource Format="TEX">\(\times\)</EquationSource> </InlineEquation> 10<InlineEquation ID="IEq5"> <EquationSource Format="TEX">\(^{-6}\)</EquationSource> </InlineEquation> RIU were reached. The analysis extended to the 1DPhC with the modified thicknesses of TiO<InlineEquation ID="IEq6"> <EquationSource Format="TEX">\(_2\)</EquationSource> </InlineEquation> layers and gas, whose RI changes in a range of 1.0002–1.0022, leads to the sensitivity and FOM in a range of 10,680–28,000 nm/RIU and 434–1217 RIU<InlineEquation ID="IEq7"> <EquationSource Format="TEX">\(^{-1}\)</EquationSource> </InlineEquation>, respectively, and to a very low LOD of 3.6 <InlineEquation ID="IEq8"> <EquationSource Format="TEX">\(\times\)</EquationSource> </InlineEquation> 10<InlineEquation ID="IEq9"> <EquationSource Format="TEX">\(^{-6}\)</EquationSource> </InlineEquation> RIU for the TM wave. This research is the demonstration of exceptional properties of the Bloch-like SW-based sensors employing metal-dielectric 1DPhCs that can be used in a simple sensing of a wide range of gaseous analytes.</p>

Ultra-high sensitivity gas sensors employing Bloch-like surface waves in a metal-dielectric one-dimensional photonic crystal

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2026年2月9日

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Michal Gryga,
Jakub Chylek,
Dalibor Ciprian,
Petr Hlubina

摘要

Bloch surface waves (BSWs), generated at the interface of a truncated one-dimensional photonic crystal (1DPhC) and the adjacent medium (analyte), are accompanied by narrow resonance dips that are very advantageous compared to too wide resonance dips associated with the surface plasmon resonance (SPR) phenomenon. Consequently, BSW-based sensors have been thoroughly studied and applied in the field of optical sensors, but their sensitivity to gaseous analytes does not outperform the sensitivity of the SPR-based sensors. One of the possible solutions to enhance the sensitivity represents a metal-dielectric 1DPhC. We report on a sensing concept for gaseous analytes based on the wavelength interrogation and resonances supported by a metal-dielectric 1DPhC in the Kretschmann configuration. For a metal-dielectric 1DPhC comprising bilayers of TiO \(_2\) /Au with a termination layer of TiO \(_2\) , we show that the Bloch-like SW-based resonances are resolved for both TE and TM waves. For the TE wave and the refractive index (RI) in a range of 1–1.0015, a sensitivity of 10,900 nm/RIU, a figure of merit (FOM) of 474 RIU \(^{-1}\) , and a limit of detection (LOD) of 9.3 \(\times\) 10 \(^{-6}\) RIU were reached. The analysis extended to the 1DPhC with the modified thicknesses of TiO \(_2\) layers and gas, whose RI changes in a range of 1.0002–1.0022, leads to the sensitivity and FOM in a range of 10,680–28,000 nm/RIU and 434–1217 RIU \(^{-1}\) , respectively, and to a very low LOD of 3.6 \(\times\) 10 \(^{-6}\) RIU for the TM wave. This research is the demonstration of exceptional properties of the Bloch-like SW-based sensors employing metal-dielectric 1DPhCs that can be used in a simple sensing of a wide range of gaseous analytes.