Scholarlink

<p>In this study, for analysis of primary aliphatic amines present in skin moisturizer samples, a dispersive micro solid phase extraction method using a mercaptoacetic acid-modified magnetic adsorbent (MAA@Fe<sub>3</sub>O<sub>4</sub>) was developed to eliminate matrix effects (while not adsorbing the studied analytes). This approach was combined with vortex-assisted liquid-liquid microextraction for the simultaneous derivatization and extraction of primary aliphatic amines present in these samples. To confirm the successful synthesis of the adsorbent, various characterization techniques were employed, including X-ray diffraction, Brunauer-Emmett-Teller surface area analysis, scanning electron microscopy, Fourier transform infrared spectrometry, energy-dispersive X-ray, thermogravimetric analysis, and vibrating sample magnetometry. ComplexGAPI software and analytical eco-scale index were employed to evaluate the greenness of the method. All key parameters affecting matrix cleanup, derivatization, and extraction were optimized. A gas chromatograph equipped with a flame ionization detector was used for the identification and quantification of the amine derivatives. The method demonstrated high unadsorbed percentage of the analytes (92–97%), significant enrichment factors (420–525), wide linear ranges (1.6–10,000&#xa0;µg L<sup>− 1</sup>), excellent precision (1.4–2.7%), and low limits of detection (0.5–0.82&#xa0;µg L<sup>− 1</sup>). This approach offered several advantages, including eco-friendliness, short extraction time, high matrix removal efficiency, simplicity, excellent precision, no need for specialized equipment, and adsorbent reusability for up to five cycles. The method also proved highly effective in the simultaneous extraction and derivatization of amines, further highlighting its potential for analytical applications.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Decreasing matrix effects for accurate analysis of primary aliphatic amines in skin moisturizers using magnetic adsorbent

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2025年3月17日

查看全文
  • Mir Ali Farajzadeh,
  • Sina Mohammad Mehri,
  • Mohammad Reza Afshar Mogaddam

摘要

In this study, for analysis of primary aliphatic amines present in skin moisturizer samples, a dispersive micro solid phase extraction method using a mercaptoacetic acid-modified magnetic adsorbent (MAA@Fe3O4) was developed to eliminate matrix effects (while not adsorbing the studied analytes). This approach was combined with vortex-assisted liquid-liquid microextraction for the simultaneous derivatization and extraction of primary aliphatic amines present in these samples. To confirm the successful synthesis of the adsorbent, various characterization techniques were employed, including X-ray diffraction, Brunauer-Emmett-Teller surface area analysis, scanning electron microscopy, Fourier transform infrared spectrometry, energy-dispersive X-ray, thermogravimetric analysis, and vibrating sample magnetometry. ComplexGAPI software and analytical eco-scale index were employed to evaluate the greenness of the method. All key parameters affecting matrix cleanup, derivatization, and extraction were optimized. A gas chromatograph equipped with a flame ionization detector was used for the identification and quantification of the amine derivatives. The method demonstrated high unadsorbed percentage of the analytes (92–97%), significant enrichment factors (420–525), wide linear ranges (1.6–10,000 µg L− 1), excellent precision (1.4–2.7%), and low limits of detection (0.5–0.82 µg L− 1). This approach offered several advantages, including eco-friendliness, short extraction time, high matrix removal efficiency, simplicity, excellent precision, no need for specialized equipment, and adsorbent reusability for up to five cycles. The method also proved highly effective in the simultaneous extraction and derivatization of amines, further highlighting its potential for analytical applications.