Scholarlink

<p>In this study, we developed a highly efficient and versatile non-heme iron complex containing a proline-based mono(phenol)amine ligand (L<sup>Pro</sup>), which was successfully immobilized within the nanospaces of SBA-15, creating a reusable biomimetic catalyst inspired by Cytochrome P450. The synthesized compounds were thoroughly characterized using a range of physicochemical techniques, including TEM, XPS, FT–IR, N<sub>2</sub> adsorption–desorption, TGA, ICP, SEM–EDX, and CHN analysis. The bio-inspired iron catalyst was evaluated for its effectiveness in oxidizing C–H bonds and converting alcohols into high-value compounds through environmentally benign procedures. Notably, the catalyst exhibited remarkable efficacy and selectivity in the oxidation of various benzylic substrates under mild conditions, utilizing a TBHP/O<sub>2</sub> oxidant system to yield ketones or carboxylic acids. Furthermore, the catalyst demonstrated exceptional activity in the direct oxidation of alcohols to carboxylic acids under ambient conditions. Importantly, the catalyst could be easily recovered from the reaction mixture and retained nearly all of its initial activity and structural integrity even after four consecutive cycles of reuse.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

A versatile bioinspired iron-based catalyst for the C–H bond and alcohol oxidations

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2025年12月23日

查看全文
  • Iraj Saberikia,
  • Elham Safaei,
  • Fariborz Mansouri,
  • Babak Karimi

摘要

In this study, we developed a highly efficient and versatile non-heme iron complex containing a proline-based mono(phenol)amine ligand (LPro), which was successfully immobilized within the nanospaces of SBA-15, creating a reusable biomimetic catalyst inspired by Cytochrome P450. The synthesized compounds were thoroughly characterized using a range of physicochemical techniques, including TEM, XPS, FT–IR, N2 adsorption–desorption, TGA, ICP, SEM–EDX, and CHN analysis. The bio-inspired iron catalyst was evaluated for its effectiveness in oxidizing C–H bonds and converting alcohols into high-value compounds through environmentally benign procedures. Notably, the catalyst exhibited remarkable efficacy and selectivity in the oxidation of various benzylic substrates under mild conditions, utilizing a TBHP/O2 oxidant system to yield ketones or carboxylic acids. Furthermore, the catalyst demonstrated exceptional activity in the direct oxidation of alcohols to carboxylic acids under ambient conditions. Importantly, the catalyst could be easily recovered from the reaction mixture and retained nearly all of its initial activity and structural integrity even after four consecutive cycles of reuse.