<p>This report highlights the development of an innovative and efficient metal-organic framework (MOF) synthesized through a hydrothermal reaction utilizing palladium acetate salt and DTPA as the organic ligand. Detailed analyses of the synthesized MOF were performed using techniques such as FT-IR, TGA, XRD, EDS, BET, SEM, and ICP. The resulting Pd-DTPA-MOF demonstrated exceptional efficiency and performance in C–S cross-coupling reactions under mild conditions. Additionally, this nanostructured material offers multiple benefits, including high product yields, a simple synthesis process, and environmentally friendly characteristics. Importantly, the versatile Pd-DTPA-MOF nanocatalyst can be easily recovered from the reaction mixture via centrifugation and reused for up to four consecutive cycles with only a slight decline in catalytic activity.</p>

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Metal-organic framework (Pd-DTPA-MOF)-based materials as heterogeneous catalysts for C–S cross-coupling reactions

  • Anjan Kumar,
  • Rana Said,
  • Munthar Kadhim Abosaoda,
  • Vicky Jain,
  • Suhas Ballal,
  • Abhayveer Singh,
  • Mamata Chahar,
  • Suman Saini,
  • Kamal Kant Joshi

摘要

This report highlights the development of an innovative and efficient metal-organic framework (MOF) synthesized through a hydrothermal reaction utilizing palladium acetate salt and DTPA as the organic ligand. Detailed analyses of the synthesized MOF were performed using techniques such as FT-IR, TGA, XRD, EDS, BET, SEM, and ICP. The resulting Pd-DTPA-MOF demonstrated exceptional efficiency and performance in C–S cross-coupling reactions under mild conditions. Additionally, this nanostructured material offers multiple benefits, including high product yields, a simple synthesis process, and environmentally friendly characteristics. Importantly, the versatile Pd-DTPA-MOF nanocatalyst can be easily recovered from the reaction mixture via centrifugation and reused for up to four consecutive cycles with only a slight decline in catalytic activity.