Scholarlink

<p>Rising global interest in environmentally friendly, high-performance polymeric materials has accelerated the innovation of next-generation polyurethane systems. This research introduces a novel bio-based waterborne polyurethane, synthesized with a vanillin-derived green polyol chain extender featuring dynamic imine linkages. Vanillin diol (VAN-OH) was synthesized using a straightforward one-step condensation of vanillin and ethylenediamine, incorporating dynamic Schiff base functionality into the compound. The waterborne polyurethane (WPU) formulation was synthesized by combining the chain extender VAN-OH, dimethylolpropionic acid (DMPA), polytetrahydrofuran (PTHF), and isophorone diisocyanate (IPDI) in the proper molar ratios. The synthesis parameters were improved through a Design of Experiments (DoE) methodology to enhance mechanical characteristics. The WPU incorporating a vanillin-derived diol chain extender (WPU-VAN-OH) films exhibited a tensile strength of 12.8&#xa0;MPa, three times greater than that of standard WPU at 4.3&#xa0;MPa, and showed exceptional self-healing capabilities, completely mending surface scratches within 30&#xa0;min at 80&#xa0;°C by dynamic imine bond exchange. The material exhibited higher thermal stability, less water absorption (22.8% compared to 32.2% for WPU after 7 days), and superior adhesion to stainless steel (18.17 kgf/cm² versus 8.23 kgf/cm² for WPU). WPU-VAN-OH films presents a sustainable and efficient methodology for formulating polyurethanes characterized by high strength, self-healing properties, and environmental compatibility, appropriate for uses including protective coatings, advanced adhesives, and flexible elastomers.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Biobased self healing waterborne polyurethane with vanillin derived dynamic Imine bonds for enhanced mechanical strength and performance

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2025年9月26日

查看全文
  • Ali Reza Banan,
  • Seyed Mojtaba Keshavarz

摘要

Rising global interest in environmentally friendly, high-performance polymeric materials has accelerated the innovation of next-generation polyurethane systems. This research introduces a novel bio-based waterborne polyurethane, synthesized with a vanillin-derived green polyol chain extender featuring dynamic imine linkages. Vanillin diol (VAN-OH) was synthesized using a straightforward one-step condensation of vanillin and ethylenediamine, incorporating dynamic Schiff base functionality into the compound. The waterborne polyurethane (WPU) formulation was synthesized by combining the chain extender VAN-OH, dimethylolpropionic acid (DMPA), polytetrahydrofuran (PTHF), and isophorone diisocyanate (IPDI) in the proper molar ratios. The synthesis parameters were improved through a Design of Experiments (DoE) methodology to enhance mechanical characteristics. The WPU incorporating a vanillin-derived diol chain extender (WPU-VAN-OH) films exhibited a tensile strength of 12.8 MPa, three times greater than that of standard WPU at 4.3 MPa, and showed exceptional self-healing capabilities, completely mending surface scratches within 30 min at 80 °C by dynamic imine bond exchange. The material exhibited higher thermal stability, less water absorption (22.8% compared to 32.2% for WPU after 7 days), and superior adhesion to stainless steel (18.17 kgf/cm² versus 8.23 kgf/cm² for WPU). WPU-VAN-OH films presents a sustainable and efficient methodology for formulating polyurethanes characterized by high strength, self-healing properties, and environmental compatibility, appropriate for uses including protective coatings, advanced adhesives, and flexible elastomers.