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<p>In the beverage industry, the CO<sub>2</sub> pressure and dissolved CO<sub>2</sub> reached in their packaged beverage play an important role. In this regard, the work aims to develop a thermodynamic model for the prediction of the phase equilibrium behavior of quaternary CO<sub>2</sub>–sugar–water-alcohol solutions up to high pressures. The Perturbed Hard Sphere Chain (PHSC) equation of state (EoS) has been used to predict the solubility of CO<sub>2</sub> in glucose-water-alcohol solutions. Glucose molecules have been modeled as a chain-like molecule with ten association sites. Cross-association between CO<sub>2</sub>, glucose, and water molecules has been considered. Temperature-dependent binary interaction parameter (BIP) has been considered to improve the model performance. The solubility of glucose in water and ethanol has been estimated at various temperatures. As well, the vapor-liquid equilibrium behavior of the ternary CO<sub>2</sub>-glucose-water system has been predicted. The results show that the model can predict the solubility of CO<sub>2</sub> in a glucose-water mixture satisfactory. In some sparking drinks, ethanol is widely used. In this regard, the prediction of CO<sub>2</sub> solubility in the water-ethanol-glucose mixture has been investigated. The vapor-liquid equilibrium of the quaternary CO<sub>2</sub>-water-ethanol-glucose system has been predicted up to 30&#xa0;MPa without using any additional adjustable parameter. The results show that, the deviation between model and experimental data in liquid and vapor phases increases by increasing ethanol concentration. The proposed model can be used for the prediction of CO<sub>2</sub> solubility and equilibrium compositions of quaternary CO<sub>2</sub>-water-ethanol-glucose system over a wide range of pressures, temperatures, and sugar (or ethanol) concentrations.</p>

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Prediction of carbon dioxide solubility in sugar-water-alcohol solutions at high pressure for application to sparkling drinks

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2026年6月2日

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  • Shaker Al-Hasnaawei,
  • Khalid Mujasam Batoo,
  • Hardik Doshi,
  • Anupam Yadav,
  • R. Roopashree,
  • Aditya Kashyap,
  • Karthikeyan Jayabalan,
  • Subhashree Ray,
  • Ahmed Ahmed Ibrahim

摘要

In the beverage industry, the CO2 pressure and dissolved CO2 reached in their packaged beverage play an important role. In this regard, the work aims to develop a thermodynamic model for the prediction of the phase equilibrium behavior of quaternary CO2–sugar–water-alcohol solutions up to high pressures. The Perturbed Hard Sphere Chain (PHSC) equation of state (EoS) has been used to predict the solubility of CO2 in glucose-water-alcohol solutions. Glucose molecules have been modeled as a chain-like molecule with ten association sites. Cross-association between CO2, glucose, and water molecules has been considered. Temperature-dependent binary interaction parameter (BIP) has been considered to improve the model performance. The solubility of glucose in water and ethanol has been estimated at various temperatures. As well, the vapor-liquid equilibrium behavior of the ternary CO2-glucose-water system has been predicted. The results show that the model can predict the solubility of CO2 in a glucose-water mixture satisfactory. In some sparking drinks, ethanol is widely used. In this regard, the prediction of CO2 solubility in the water-ethanol-glucose mixture has been investigated. The vapor-liquid equilibrium of the quaternary CO2-water-ethanol-glucose system has been predicted up to 30 MPa without using any additional adjustable parameter. The results show that, the deviation between model and experimental data in liquid and vapor phases increases by increasing ethanol concentration. The proposed model can be used for the prediction of CO2 solubility and equilibrium compositions of quaternary CO2-water-ethanol-glucose system over a wide range of pressures, temperatures, and sugar (or ethanol) concentrations.