<p>Reaching lasing in electrically pumped microdevices based on solution-processed semiconductors poses a substantial scientific and technological challenge. Halide perovskites offer a promising platform for electrical injection<sup><CitationRef CitationID="CR1">1</CitationRef></sup>, as their optically excited single-crystal cavities<sup><CitationRef AdditionalCitationIDS="CR3" CitationID="CR2">2</CitationRef>–<CitationRef CitationID="CR4">4</CitationRef></sup> and predesigned<sup><CitationRef CitationID="CR5">5</CitationRef>,<CitationRef CitationID="CR6">6</CitationRef></sup> or postprocessed microstructures<sup><CitationRef CitationID="CR7">7</CitationRef>,<CitationRef CitationID="CR8">8</CitationRef></sup> have exhibited low lasing threshold. Indirect electrical pumping of a dual-cavity perovskite laser was recently obtained<sup><CitationRef CitationID="CR9">9</CitationRef></sup>, using a well-established technological concept of embedding a high-luminosity light-emitting diode (LED) with a high-gain medium into an integrated device<sup><CitationRef CitationID="CR10">10</CitationRef></sup>. Direct charge-carrier injection into a perovskite LED excited by auxiliary short, optical pulses resulted in amplified spontaneous emission (ASE)<sup><CitationRef CitationID="CR11">11</CitationRef></sup>. Other efforts for rational engineering of architectures<sup><CitationRef AdditionalCitationIDS="CR13 CR14" CitationID="CR12">12</CitationRef>–<CitationRef CitationID="CR15">15</CitationRef></sup> that allow for high charge-carrier density are still to demonstrate lasing. Here we develop a new strategy for achieving direct electrical pumping of a perovskite laser. We integrate a solution-grown CsPbBr<sub>3</sub> microplate with chemically inert single-walled carbon nanotube (SWCNT) electrodes and embed them into an optical microcavity. By cooling the microdevice down to 8 K at a constant current, a perovskite p–i–n diode is formed that facilitates a balanced carrier injection at high current densities. The perovskite microcavity diode operates in the strong coupling regime, exhibiting polariton lasing under a direct current of 65 μA.</p>

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Non-epitaxial perovskite polariton laser diode operating under direct current

  • Anatoly P. Pushkarev,
  • Daria Khmelevskaia,
  • Ivan A. Matchenya,
  • Stepan A. Baryshev,
  • Denis A. Sannikov,
  • Alexey A. Ekgardt,
  • Eduard I. Moiseev,
  • Natalia V. Kryzhanovskaya,
  • Alexey E. Zhukov,
  • Dmitry V. Krasnikov,
  • Alexandr A. Marunchenko,
  • Alexey V. Yulin,
  • Albert G. Nasibulin,
  • Pavlos G. Lagoudakis

摘要

Reaching lasing in electrically pumped microdevices based on solution-processed semiconductors poses a substantial scientific and technological challenge. Halide perovskites offer a promising platform for electrical injection1, as their optically excited single-crystal cavities24 and predesigned5,6 or postprocessed microstructures7,8 have exhibited low lasing threshold. Indirect electrical pumping of a dual-cavity perovskite laser was recently obtained9, using a well-established technological concept of embedding a high-luminosity light-emitting diode (LED) with a high-gain medium into an integrated device10. Direct charge-carrier injection into a perovskite LED excited by auxiliary short, optical pulses resulted in amplified spontaneous emission (ASE)11. Other efforts for rational engineering of architectures1215 that allow for high charge-carrier density are still to demonstrate lasing. Here we develop a new strategy for achieving direct electrical pumping of a perovskite laser. We integrate a solution-grown CsPbBr3 microplate with chemically inert single-walled carbon nanotube (SWCNT) electrodes and embed them into an optical microcavity. By cooling the microdevice down to 8 K at a constant current, a perovskite p–i–n diode is formed that facilitates a balanced carrier injection at high current densities. The perovskite microcavity diode operates in the strong coupling regime, exhibiting polariton lasing under a direct current of 65 μA.