<p>Magnetic states with zero magnetization but non-relativistic spin splitting are outstanding candidates for the next generation of spintronic devices. Their electronvolt (eV)-scale spin splitting, ultrafast spin dynamics and nearly vanishing stray fields make them particularly promising for several applications<sup><CitationRef CitationID="CR1">1</CitationRef>,<CitationRef CitationID="CR2">2</CitationRef></sup>. A variety of such magnetic states with non-trivial spin textures have been identified recently, including even-parity <i>d</i>-wave, <i>g</i>-wave or <i>i</i>-wave altermagnets and odd-parity <i>p</i>-wave magnets<sup><CitationRef AdditionalCitationIDS="CR4 CR5 CR6" CitationID="CR3">3</CitationRef>–<CitationRef CitationID="CR7">7</CitationRef></sup>. Achieving voltage-based control of the non-uniform spin polarization of these magnetic states is of great interest for realizing energy-efficient and compact devices for information storage and processing<sup><CitationRef CitationID="CR8">8</CitationRef>,<CitationRef CitationID="CR9">9</CitationRef></sup>. Spin-spiral type II multiferroics are optimal candidates for such voltage-based control, as they exhibit an inversion-symmetry-breaking magnetic order that directly induces ferroelectric polarization, allowing for symmetry-protected cross-control between spin chirality and polar order<sup><CitationRef AdditionalCitationIDS="CR11 CR12 CR13" CitationID="CR10">10</CitationRef>–<CitationRef CitationID="CR14">14</CitationRef></sup>. Here we combine photocurrent measurements, first-principles calculations and group-theory analysis to provide direct evidence that the spin polarization of the spin-spiral type II multiferroic NiI<sub>2</sub> exhibits odd-parity character connected to the spiral chirality. The symmetry-protected coupling between chirality and polar order enables electrical control of a primarily non-relativistic spin polarization. Our findings represent an observation of <i>p</i>-wave&#xa0;magnetism in a spin-spiral type II multiferroic, which may lead to the development of voltage-based switching of non-relativistic spin polarization in compensated magnets.</p>

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Electrical switching of a p-wave magnet 

  • Qian Song,
  • Srdjan Stavrić,
  • Paolo Barone,
  • Andrea Droghetti,
  • Daniil S. Antonenko,
  • Jörn W. F. Venderbos,
  • Connor A. Occhialini,
  • Batyr Ilyas,
  • Emre Ergeçen,
  • Nuh Gedik,
  • Sang-Wook Cheong,
  • Rafael M. Fernandes,
  • Silvia Picozzi,
  • Riccardo Comin

摘要

Magnetic states with zero magnetization but non-relativistic spin splitting are outstanding candidates for the next generation of spintronic devices. Their electronvolt (eV)-scale spin splitting, ultrafast spin dynamics and nearly vanishing stray fields make them particularly promising for several applications1,2. A variety of such magnetic states with non-trivial spin textures have been identified recently, including even-parity d-wave, g-wave or i-wave altermagnets and odd-parity p-wave magnets37. Achieving voltage-based control of the non-uniform spin polarization of these magnetic states is of great interest for realizing energy-efficient and compact devices for information storage and processing8,9. Spin-spiral type II multiferroics are optimal candidates for such voltage-based control, as they exhibit an inversion-symmetry-breaking magnetic order that directly induces ferroelectric polarization, allowing for symmetry-protected cross-control between spin chirality and polar order1014. Here we combine photocurrent measurements, first-principles calculations and group-theory analysis to provide direct evidence that the spin polarization of the spin-spiral type II multiferroic NiI2 exhibits odd-parity character connected to the spiral chirality. The symmetry-protected coupling between chirality and polar order enables electrical control of a primarily non-relativistic spin polarization. Our findings represent an observation of p-wave magnetism in a spin-spiral type II multiferroic, which may lead to the development of voltage-based switching of non-relativistic spin polarization in compensated magnets.