Intermediate phase evolution for stable and oriented evaporated wide-bandgap perovskite solar cells
摘要
Efficient wide-bandgap perovskite solar cells have pushed tandem efficiencies to 34.9%, reinforcing their promise for next-generation photovoltaics. However, their commercial adoption is hindered by stability issues of wide-bandgap perovskites, especially under high-temperature maximum power point tracking conditions. Here we report the stabilization of ~1.7-eV wide-bandgap perovskites via intermediate phase evolution, enabling a self-guided crystal-growth mode. A CsI2Br intermediate phase forms during early stage deposition, directing the oriented growth of polycrystalline films with unique texturing. Atomic-scale scanning transmission electron microscopy reveals that the CsI2Br