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<p>Physical and chemical properties of passivating alteration gels formed on alumino-boro-silicate glasses of interest for nuclear waste containment are reported. Opposite effects of B and Al on the gel’s propensity to restructure and become passivating were observed. Boron, primarily forming Si‒O‒B bonds, fragments and weakens the silicate network if its concentration is higher than a critical value, leading to the formation of pores and Si‒OH terminations as it leaches out. The greater the number of the silanol groups, the more effective the recondensation (Si‒OH + Si‒OH ⇌ Si‒O‒Si + H<sub>2</sub>O) is, leading to reduction of pore connectivity; this facilitates passivation and thus lowers the glass alteration rate. Conversely, Al has a slowing effect on this reorganization dynamics. This work provides better insight into the role of elements in the glass alteration kinetics.</p>

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Impact of B and Al on the initial and residual dissolution rate of alumino-boro-silicate glasses. Part II: gel properties

  • 期刊论文

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  • 发表日期：

    2025年5月22日

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  • Mélanie Taron,
  • Stéphane Gin,
  • Huseyin Kaya,
  • Jean-Marc Delaye,
  • Seong H. Kim

摘要

Physical and chemical properties of passivating alteration gels formed on alumino-boro-silicate glasses of interest for nuclear waste containment are reported. Opposite effects of B and Al on the gel’s propensity to restructure and become passivating were observed. Boron, primarily forming Si‒O‒B bonds, fragments and weakens the silicate network if its concentration is higher than a critical value, leading to the formation of pores and Si‒OH terminations as it leaches out. The greater the number of the silanol groups, the more effective the recondensation (Si‒OH + Si‒OH ⇌ Si‒O‒Si + H2O) is, leading to reduction of pore connectivity; this facilitates passivation and thus lowers the glass alteration rate. Conversely, Al has a slowing effect on this reorganization dynamics. This work provides better insight into the role of elements in the glass alteration kinetics.