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<p>Colloidal molecules (CMs) are assemblies of nanoparticles (NPs) that accurately replicate the structure and symmetry of actual molecules. Regarded as modular building blocks, CMs enable the creation of hierarchical structures that are challenging to achieve through the direct self-assembly of individual NPs. However, the limited availability of efficient and scalable methods for nanoscale CM synthesis has constrained their broader use in constructing hierarchical structures. Here we show that long-range electrostatic attraction, combined with short-range hydrogen-bonding interactions, enables the assembly of binary NPs into CMs in an aqueous medium, attaining high yields of up to 95% and concentrations three orders of magnitude higher than previously reported values. These CMs can serve as building blocks for constructing CM arrays and non-close-packed hierarchical structures with open pores. Our approach marks an efficient self-assembly strategy for fabricating nanoscale CMs and demonstrates their potential in constructing innovative hierarchical structures.</p>

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Highly scalable, dialysis-controlled synthesis of colloidal molecules via regulated self-assembly of polymer-grafted gold nanoparticles

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2026年7月25日

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  • Huibin He,
  • Chongyang Yao,
  • Xiaoxue Shen,
  • Jing Tao,
  • Di Zheng,
  • Liwei Dai,
  • Runshi Qiao,
  • Yutao Sang,
  • Zhihong Nie

摘要

Colloidal molecules (CMs) are assemblies of nanoparticles (NPs) that accurately replicate the structure and symmetry of actual molecules. Regarded as modular building blocks, CMs enable the creation of hierarchical structures that are challenging to achieve through the direct self-assembly of individual NPs. However, the limited availability of efficient and scalable methods for nanoscale CM synthesis has constrained their broader use in constructing hierarchical structures. Here we show that long-range electrostatic attraction, combined with short-range hydrogen-bonding interactions, enables the assembly of binary NPs into CMs in an aqueous medium, attaining high yields of up to 95% and concentrations three orders of magnitude higher than previously reported values. These CMs can serve as building blocks for constructing CM arrays and non-close-packed hierarchical structures with open pores. Our approach marks an efficient self-assembly strategy for fabricating nanoscale CMs and demonstrates their potential in constructing innovative hierarchical structures.