Scholarlink

<p>Solid-state electrolytes (SSEs) are the essential component of all-solid-state batteries (ASSBs). Designing better SSEs holds the key to the success of the ASSBs. Here, this study effectively realises the design of SSEs through functional modules. Various functional designs have been achieved by incorporating different functional models. Here, we initially introduce LaCl<sub>3</sub>, which possesses a UCl<sub>3</sub> structure, as a functional module to demonstrate the feasibility of our approach. The Li<sub>2</sub>O-1.8TaCl<sub>5</sub>-0.2LaCl<sub>3</sub> (LTLOC) SSE enable the ASSB with LiNi<sub>0.88</sub>Co<sub>0.09</sub>Mn<sub>0.03</sub>O<sub>2</sub> (NCM88) to exhibit stable cycling and stable operation at low temperature (−30 °C). Additionally, various types of functional modules, including chloride, oxide, and fluoride, have been successfully introduced, further supporting the universality of amorphous functional module design. Furthermore, the incorporation of low-cost and low-density AlF<sub>3</sub> highlights the benefits of this design approach, as it allows for a high proportion of fluoride to be introduced without compromising ionic conductivity. Li<sub>2</sub>O-1.8TaCl<sub>5</sub>-5AlF<sub>3</sub> (LTOC-5AlF<sub>3</sub>) exhibits stability in humid conditions, resistance to high voltage, and compatibility with lithium metal simultaneously. The key strength of this design approach is its ability to maintain advantages and make up for the shortcomings.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Functional modules for enhanced amorphous composite halide solid electrolytes for low-temperature all-solid-state lithium batteries

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2026年5月27日

查看全文
  • Yanlong Wu,
  • Xinmiao Wang,
  • Xingyu Wang,
  • Yulong Cai,
  • Junyi Yue,
  • Simeng Zhang,
  • Xiangzhen Zhu,
  • Shanshan Wang,
  • Meng Li,
  • Xu Han,
  • Yi Duan,
  • Changtai Zhao,
  • Rong Yang,
  • Jianwen Liang,
  • Xiaona Li,
  • Xueliang Sun,
  • Jiantao Wang

摘要

Solid-state electrolytes (SSEs) are the essential component of all-solid-state batteries (ASSBs). Designing better SSEs holds the key to the success of the ASSBs. Here, this study effectively realises the design of SSEs through functional modules. Various functional designs have been achieved by incorporating different functional models. Here, we initially introduce LaCl3, which possesses a UCl3 structure, as a functional module to demonstrate the feasibility of our approach. The Li2O-1.8TaCl5-0.2LaCl3 (LTLOC) SSE enable the ASSB with LiNi0.88Co0.09Mn0.03O2 (NCM88) to exhibit stable cycling and stable operation at low temperature (−30 °C). Additionally, various types of functional modules, including chloride, oxide, and fluoride, have been successfully introduced, further supporting the universality of amorphous functional module design. Furthermore, the incorporation of low-cost and low-density AlF3 highlights the benefits of this design approach, as it allows for a high proportion of fluoride to be introduced without compromising ionic conductivity. Li2O-1.8TaCl5-5AlF3 (LTOC-5AlF3) exhibits stability in humid conditions, resistance to high voltage, and compatibility with lithium metal simultaneously. The key strength of this design approach is its ability to maintain advantages and make up for the shortcomings.