<p>Textured piezoelectric ceramics are considered promising next-generation piezoelectric materials, offering single-crystal-like high piezoelectric performance and low production cost. However, the large grain size of textured ceramics (15 ~ 40 μm) lead to significant decrease in piezoelectricity as the thickness of samples approaches the scale of grain size, limiting their application in high-frequency transducers (&gt;20 MHz, corresponding thickness &lt;100 μm). Here, we address this issue by reducing the grain size through template shortening. A modified topochemical microcrystal conversion method was developed to fabricate BaTiO<sub>3</sub> templates with a much smaller length of 2.7 μm, compared with conventional templates (&gt;7 μm). Using these reduced-size developed templates, we obtained &lt;001 &gt; -textured Pb(Mg<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub>-PbTiO<sub>3</sub> ceramic with an average grain size of 7.8 μm, being significantly smaller than previously reported textured Pb(Mg<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub>-PbTiO<sub>3</sub> ceramics (~20 μm), while achieving a high piezoelectric coefficient <i>d</i><sub>33</sub> of 1330 pC N<sup>-1</sup>. Notably, the adverse thickness scaling effect on piezoelectric performance was greatly mitigated: at a thickness of 100 μm, the piezoelectric response was found to reduce only 8% for our textured ceramics with reduced grain size, compared with almost 30% in conventional-grain-size textured ceramics. This strategy provides a practical route to high-performance textured ceramics suited for next-generation high-frequency ultrasonic transducers.</p>

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Textured piezoelectric ceramics with reduced grain size for high-frequency transducer applications

  • Yizhou Xiao,
  • Shuai Yang,
  • Mingwen Wang,
  • Yaolin Wang,
  • Tao Li,
  • Chunchun Li,
  • Jinglei Li,
  • Fei Li

摘要

Textured piezoelectric ceramics are considered promising next-generation piezoelectric materials, offering single-crystal-like high piezoelectric performance and low production cost. However, the large grain size of textured ceramics (15 ~ 40 μm) lead to significant decrease in piezoelectricity as the thickness of samples approaches the scale of grain size, limiting their application in high-frequency transducers (>20 MHz, corresponding thickness <100 μm). Here, we address this issue by reducing the grain size through template shortening. A modified topochemical microcrystal conversion method was developed to fabricate BaTiO3 templates with a much smaller length of 2.7 μm, compared with conventional templates (>7 μm). Using these reduced-size developed templates, we obtained <001 > -textured Pb(Mg1/3Nb2/3)O3-PbTiO3 ceramic with an average grain size of 7.8 μm, being significantly smaller than previously reported textured Pb(Mg1/3Nb2/3)O3-PbTiO3 ceramics (~20 μm), while achieving a high piezoelectric coefficient d33 of 1330 pC N-1. Notably, the adverse thickness scaling effect on piezoelectric performance was greatly mitigated: at a thickness of 100 μm, the piezoelectric response was found to reduce only 8% for our textured ceramics with reduced grain size, compared with almost 30% in conventional-grain-size textured ceramics. This strategy provides a practical route to high-performance textured ceramics suited for next-generation high-frequency ultrasonic transducers.