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<p>Next generation high speed, large torque, rotating electrical machines demand materials with an excellent balance of magnetic and mechanical properties. High entropy alloys (HEAs) can exhibit this unique combination of properties, e.g., CoFeNi based HEAs containing Ta. The high Ta content makes these alloys prohibitively expensive for industrial applications. Hence, we develop Ta free HEA using a thermodynamic approach. The addition of Al and Ti to the base CoFeNi alloy is studied. We investigate two compositions: Ti<sub>0.24</sub>CoFeNi<sub>0.78</sub> and Al<sub>0.3</sub>Ti<sub>0.2</sub>CoFeNi. In their solution treated and quenched condition these HEAs exhibit a low coercivity <i>H</i><sub><i>c</i></sub> ~ 1.8–2.4 Oe, high saturation magnetization <i>M</i><sub><i>s</i></sub> ~ 96.5-137.3 emu/g, coupled with a high yield strength, YS ~ 780-850 MPa, ultimate tensile strength, UTS ~ 1200 MPa, large tensile elongation, ε ~ 29-35%, and with desired high electrical resistivity ( ~ 269.5-308.3 µΩ·cm), making them attractive for high frequency electrical machines. Importantly, the latter HEA is further strengthened to a very high YS ~ 1140-1200 MPa with excellent ductility (ε ~ 18-25%) and electrical resistivity (296.1-459.3 µΩ·cm), but at the cost of higher <i>H</i><sub><i>c</i></sub> values ~ 8.8-48.6 Oe.</p>

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A magnetically soft yet mechanically strong and ductile Ta free CoFeNi high entropy alloy with Al and Ti additions

  • 期刊论文

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  • 发表日期：

    2026年2月5日

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  • Sudip Kumar Sarkar,
  • Nachiket Keskar,
  • Li Ping Tan,
  • Tirthesh Ingale,
  • Advika Chesetti,
  • Sriswaroop Dasari,
  • Karl P. Davidson,
  • V. Chaudhary,
  • Narendra Dahotre,
  • R. V. Ramanujan,
  • Rajarshi Banerjee

摘要

Next generation high speed, large torque, rotating electrical machines demand materials with an excellent balance of magnetic and mechanical properties. High entropy alloys (HEAs) can exhibit this unique combination of properties, e.g., CoFeNi based HEAs containing Ta. The high Ta content makes these alloys prohibitively expensive for industrial applications. Hence, we develop Ta free HEA using a thermodynamic approach. The addition of Al and Ti to the base CoFeNi alloy is studied. We investigate two compositions: Ti0.24CoFeNi0.78 and Al0.3Ti0.2CoFeNi. In their solution treated and quenched condition these HEAs exhibit a low coercivity Hc ~ 1.8–2.4 Oe, high saturation magnetization Ms ~ 96.5-137.3 emu/g, coupled with a high yield strength, YS ~ 780-850 MPa, ultimate tensile strength, UTS ~ 1200 MPa, large tensile elongation, ε ~ 29-35%, and with desired high electrical resistivity ( ~ 269.5-308.3 µΩ·cm), making them attractive for high frequency electrical machines. Importantly, the latter HEA is further strengthened to a very high YS ~ 1140-1200 MPa with excellent ductility (ε ~ 18-25%) and electrical resistivity (296.1-459.3 µΩ·cm), but at the cost of higher Hc values ~ 8.8-48.6 Oe.