Scholarlink

<p>Developing circularly polarized organic light-emitting diodes (CP-OLEDs) that simultaneously achieve narrow-spectrum emission and high electroluminescence (EL) efficiency remains a formidable challenge. This work prepares two pairs of efficient circularly polarized thermally activated delayed fluorescence (CP-TADF) materials, featuring high photoluminescence quantum yields, short delayed fluorescence lifetimes, good luminescence dissymmetry factors and large horizontal dipole ratios. They can function as emitters for efficient sky-blue CP-OLEDs, providing high maximum external quantum efficiencies (<i>η</i><sub>ext,max</sub>s) (33.8%) and good EL dissymmetry factors (<i>g</i><sub>EL</sub>s) (−2.64 × 10<sup>−3</sup>). More importantly, they can work as sensitizers for achiral multi-resonance (MR) TADF emitters, furnishing high-performance blue and green hyperfluorescence (HF) CP-OLEDs with intense narrow-spectrum CP-EL and good <i>η</i><sub>ext,max</sub>s (31.4%). Moreover, tandem HF CP-OLEDs are fabricated for the first time by employing CP-TADF sensitizers and achiral MR-TADF emitters, which radiate narrow-spectrum CP-EL with an extraordinary <i>η</i><sub>ext,max</sub>s (51.3%) and good <i>g</i><sub>EL</sub>s (4.87 × 10<sup>−3</sup>). The circularly polarized energy transfer as well as chirality-induced spin selectivity effect of CP-TADF sensitizers are considered to contribute greatly to the generation of efficient CP-EL from achiral MR-TADF emitters. This work not only explores efficient CP-TADF materials but also provides a facile approach to construct HF CP-OLEDs with achiral MR-TADF emitters.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Hyperfluorescence circularly polarized OLEDs consisting of chiral TADF sensitizers and achiral multi-resonance emitters

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2025年2月15日

查看全文
  • Letian Chen,
  • Peng Zou,
  • Jinke Chen,
  • Letian Xu,
  • Ben Zhong Tang,
  • Zujin Zhao

摘要

Developing circularly polarized organic light-emitting diodes (CP-OLEDs) that simultaneously achieve narrow-spectrum emission and high electroluminescence (EL) efficiency remains a formidable challenge. This work prepares two pairs of efficient circularly polarized thermally activated delayed fluorescence (CP-TADF) materials, featuring high photoluminescence quantum yields, short delayed fluorescence lifetimes, good luminescence dissymmetry factors and large horizontal dipole ratios. They can function as emitters for efficient sky-blue CP-OLEDs, providing high maximum external quantum efficiencies (ηext,maxs) (33.8%) and good EL dissymmetry factors (gELs) (−2.64 × 10−3). More importantly, they can work as sensitizers for achiral multi-resonance (MR) TADF emitters, furnishing high-performance blue and green hyperfluorescence (HF) CP-OLEDs with intense narrow-spectrum CP-EL and good ηext,maxs (31.4%). Moreover, tandem HF CP-OLEDs are fabricated for the first time by employing CP-TADF sensitizers and achiral MR-TADF emitters, which radiate narrow-spectrum CP-EL with an extraordinary ηext,maxs (51.3%) and good gELs (4.87 × 10−3). The circularly polarized energy transfer as well as chirality-induced spin selectivity effect of CP-TADF sensitizers are considered to contribute greatly to the generation of efficient CP-EL from achiral MR-TADF emitters. This work not only explores efficient CP-TADF materials but also provides a facile approach to construct HF CP-OLEDs with achiral MR-TADF emitters.