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<p>Self-assembled monolayers (SAMs) have displayed unpredictable potential in efficient perovskite solar cells (PSCs). Yet most of SAMs are largely suitable for pure Pb-based devices, precisely developing promising hole-selective contacts (HSCs) for Sn-based PSCs and exploring the underlying general mechanism are fundamentally desired. Here, based on the prototypical donor-acceptor SAM MPA-BT-BA (BT), oligoether side chains with different length (i.e., methoxy, 2-methoxyethoxy, 2-(2-methoxyethoxy)ethoxy group) were custom-introduced on the benzothiadiazole unit to produce the target SAMs with acronyms MPA-MBT-BA (MBT), MPA-EBT-BA (EBT), and MPA-MEBT-BA (MEBT), respectively, and acting as HSCs for efficient Sn-Pb PSCs and all-perovskite tandems. The introduction of oligoether side chains enables HSCs effectively accelerate hole extraction, regulate the crystal growth and passivate surface defects of Sn-Pb perovskites. In particular, benefiting from the enhanced Sn-Pb perovskite film quality and the suppressed interfacial non-radiative recombination losses, EBT-tailored LBG devices yield a champion efficiency of 23.54%, enabling 28.61% efficient monolithic all-perovskite tandems with an impressive <i>V</i><sub>OC</sub> of 2.155 V and excellent operational stability as well as 28.22%-efficiency 4-T tandems.</p>

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Self-assembled hole-selective contact for efficient Sn-Pb perovskite solar cells and all-perovskite tandems

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年1月2日

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  • Jingwei Zhu,
  • Xiaozhen Huang,
  • Yi Luo,
  • Wenbo Jiao,
  • Yuliang Xu,
  • Juncheng Wang,
  • Zhiyu Gao,
  • Kun Wei,
  • Tianshu Ma,
  • Jiayu You,
  • Jialun Jin,
  • Shenghan Wu,
  • Zhihao Zhang,
  • Wenqing Liang,
  • Yang Wang,
  • Shengqiang Ren,
  • Changlei Wang,
  • Cong Chen,
  • Jinbao Zhang,
  • Dewei Zhao

摘要

Self-assembled monolayers (SAMs) have displayed unpredictable potential in efficient perovskite solar cells (PSCs). Yet most of SAMs are largely suitable for pure Pb-based devices, precisely developing promising hole-selective contacts (HSCs) for Sn-based PSCs and exploring the underlying general mechanism are fundamentally desired. Here, based on the prototypical donor-acceptor SAM MPA-BT-BA (BT), oligoether side chains with different length (i.e., methoxy, 2-methoxyethoxy, 2-(2-methoxyethoxy)ethoxy group) were custom-introduced on the benzothiadiazole unit to produce the target SAMs with acronyms MPA-MBT-BA (MBT), MPA-EBT-BA (EBT), and MPA-MEBT-BA (MEBT), respectively, and acting as HSCs for efficient Sn-Pb PSCs and all-perovskite tandems. The introduction of oligoether side chains enables HSCs effectively accelerate hole extraction, regulate the crystal growth and passivate surface defects of Sn-Pb perovskites. In particular, benefiting from the enhanced Sn-Pb perovskite film quality and the suppressed interfacial non-radiative recombination losses, EBT-tailored LBG devices yield a champion efficiency of 23.54%, enabling 28.61% efficient monolithic all-perovskite tandems with an impressive VOC of 2.155 V and excellent operational stability as well as 28.22%-efficiency 4-T tandems.