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<p>The control of the microstructure of polymers derived from conjugated dienes was investigated using coordination polymerization. In this work, we conducted coordination polymerization of (<i>Z</i>)-1-phenyl[3]dendralene (1Z-P3D) as a diene monomer. The polymerization of 1Z-P3D using a homogeneous neodymium catalyst yielded poly(1Z-P3D) with predominantly 4,6-structures (~100%).</p>

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Coordination polymerization of (Z)-1-phenyl[3]dendralene by a neodymium catalyst

  • 期刊论文

  • 发表日期：

    2025年5月2日

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  • Haruto Tanaka,
  • Tomoyuki Toda,
  • Katsuhiko Takenaka

摘要

The control of the microstructure of polymers derived from conjugated dienes was investigated using coordination polymerization. In this work, we conducted coordination polymerization of (Z)-1-phenyl[3]dendralene (1Z-P3D) as a diene monomer. The polymerization of 1Z-P3D using a homogeneous neodymium catalyst yielded poly(1Z-P3D) with predominantly 4,6-structures (~100%).