<p>In authentication studies, chemists, scientists, art historians, conservators, and law enforcement collaborate to identify forgeries. For paintings, pigment characterization (detecting anachronistic materials) is decisive. Portable X-ray fluorescence spectrometry (pXRF) is a dominant, versatile, non-destructive identification method, yet its misuse is documented and widespread. Literature and current results require contextualization by instrument and era, avoiding over-interpretation. This practical review examines pXRF’s strengths and constraints through case studies.</p>

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Portable XRF for paintings and metals authentication: a critical guide to some practical limitations and multi-technique integrations

  • Marco Nicola,
  • Luca Matullo,
  • Alessandro Marello,
  • Chiara Mastrippolito,
  • Roberto Gobetto

摘要

In authentication studies, chemists, scientists, art historians, conservators, and law enforcement collaborate to identify forgeries. For paintings, pigment characterization (detecting anachronistic materials) is decisive. Portable X-ray fluorescence spectrometry (pXRF) is a dominant, versatile, non-destructive identification method, yet its misuse is documented and widespread. Literature and current results require contextualization by instrument and era, avoiding over-interpretation. This practical review examines pXRF’s strengths and constraints through case studies.