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<p>Egyptian blue (EB) is a heterogeneous multi-phase blue pigment originating in Egypt ≈5000 years ago. While cuprorivaite (CaCuSi<sub>4</sub>O<sub>10</sub>) is the primary chromophore, color of the powdered pigment depends upon multiple factors, including other phases and particle size. In this study, we synthesized EB using differing raw materials and heating times and investigated the phases and microstructure of the particles via X-ray diffraction, electron beam X-ray microanalysis, and X-ray nano-computed tomography. We measured color by reflectance visible/near-infrared spectrometry and color coordinate extraction and obtained comparative measurements on modern pigments, two Egyptian artifacts (≈2300–3400 years old), and synthesized Cu-doped glasses. Photoluminescence mapping of the artifacts confirmed intergrowth of cuprorivaite encased within colorless particles which otherwise appear as a single phase. This accurate determination of color coupled with correlation to phase distribution provides a series of recipes for obtaining given colors, knowledge which is useful for archeologists and conservation scientists working with EB materials.</p><p></p>

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Assessment of process variability and color in synthesized and ancient Egyptian blue pigments

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年5月22日

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  • John S. McCloy,
  • Edward P. Vicenzi,
  • Thomas Lam,
  • Julia Esakoff,
  • Travis A. Olds,
  • Lisa S. Haney,
  • Mostafa Sherif,
  • John Bussey,
  • M. C. Dixon Wilkins,
  • Sam Karcher

摘要

Egyptian blue (EB) is a heterogeneous multi-phase blue pigment originating in Egypt ≈5000 years ago. While cuprorivaite (CaCuSi4O10) is the primary chromophore, color of the powdered pigment depends upon multiple factors, including other phases and particle size. In this study, we synthesized EB using differing raw materials and heating times and investigated the phases and microstructure of the particles via X-ray diffraction, electron beam X-ray microanalysis, and X-ray nano-computed tomography. We measured color by reflectance visible/near-infrared spectrometry and color coordinate extraction and obtained comparative measurements on modern pigments, two Egyptian artifacts (≈2300–3400 years old), and synthesized Cu-doped glasses. Photoluminescence mapping of the artifacts confirmed intergrowth of cuprorivaite encased within colorless particles which otherwise appear as a single phase. This accurate determination of color coupled with correlation to phase distribution provides a series of recipes for obtaining given colors, knowledge which is useful for archeologists and conservation scientists working with EB materials.