Scholarlink

<p>We synthesized and studied an organoboron complex which has a three-dimensional A–D–A structure, <b>2BF</b><sub><b>2</b></sub>, and is composed of two dihydrodioxaborinine ring moieties linked by [2.2]paracyclophane. In solution, <b>2BF</b><sub><b>2</b></sub> exhibits dual fluorescence, with one band displaying solvatofluorochromism and the other not. Theoretical calculations revealed that the dual fluorescence of <b>2BF</b><sub><b>2</b></sub> derives from co exsistence of centrosymmetric and non-centrosymmetric conformers in the excited singlet state, which exhibit contrasting emission behaviors owing to their different symmetry characteristics and dipole moments.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

A three-dimensional A–D–A structured, [2.2]paracyclophane linked organoboron complex displays masked dual fluorescence and solvatofluorochromism

  • 期刊论文

  • 发表日期：

    2026年4月17日

查看全文
  • Shun Irii,
  • Takuya Ogaki,
  • Yasunori Matsui,
  • Hiroshi Ikeda

摘要

We synthesized and studied an organoboron complex which has a three-dimensional A–D–A structure, 2BF2, and is composed of two dihydrodioxaborinine ring moieties linked by [2.2]paracyclophane. In solution, 2BF2 exhibits dual fluorescence, with one band displaying solvatofluorochromism and the other not. Theoretical calculations revealed that the dual fluorescence of 2BF2 derives from co exsistence of centrosymmetric and non-centrosymmetric conformers in the excited singlet state, which exhibit contrasting emission behaviors owing to their different symmetry characteristics and dipole moments.