Scholarlink

<p>We carried out a systematic investigation on solvent-dependent spectroscopic and photophysical properties of diphenylamine (DPA) including singlet (Δ<i>E</i><sup>(0,0)</sup>) and triplet (Δ<i>E</i>(triplet)) excited states as well as the triplet decay rate constant (<i>k</i><sub>T</sub>), by following both single and multiparametric approaches. Analyses of the obtained data as well as the interpretation of sign and magnitude of the regression coefficients allowed for the understanding how the specific and non-specific solvent properties impact on the thermodynamic (Δ<i>E</i>) and kinetic (<i>k</i><sub>T</sub>) parameters related to the photochemical behaviour of DPA.</p> Graphical abstract <p>Single and multiparametric methods led to understand how the specific and non-specific solvent properties impact on the thermodynamic (Δ<i>E</i><sup>(0,0)</sup> and Δ<i>E</i>(Triplet)) and kinetic (<i>k</i><sub>T</sub>) parameters of the probe DPA through the interpretation of sign and magnitude of the regression coefficients.</p> <p></p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Simple and multiparametric approaches to correlate the solvent effect on the spectroscopic and kinetic parameters of diphenylamine

  • 期刊论文

  • 发表日期：

    2025年7月5日

查看全文
  • Sergio M. Bonesi,
  • Stefano Protti

摘要

We carried out a systematic investigation on solvent-dependent spectroscopic and photophysical properties of diphenylamine (DPA) including singlet (ΔE(0,0)) and triplet (ΔE(triplet)) excited states as well as the triplet decay rate constant (kT), by following both single and multiparametric approaches. Analyses of the obtained data as well as the interpretation of sign and magnitude of the regression coefficients allowed for the understanding how the specific and non-specific solvent properties impact on the thermodynamic (ΔE) and kinetic (kT) parameters related to the photochemical behaviour of DPA.

Graphical abstract

Single and multiparametric methods led to understand how the specific and non-specific solvent properties impact on the thermodynamic (ΔE(0,0) and ΔE(Triplet)) and kinetic (kT) parameters of the probe DPA through the interpretation of sign and magnitude of the regression coefficients.