<p>One-dimensional Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub>:Er<sup>3+</sup>/Ho<sup>3+</sup> nanostructures have been successfully synthesized via a conventional electrospinning technique. Their diameters are in the range of 200–300&#xa0;nm. The Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub>:Er<sup>3+</sup>/Ho<sup>3+</sup> nanostructures exhibit variable emissions under different excitation wavelengths. Under 377&#xa0;nm excitation, the Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub>: Er<sup>3+</sup>/Ho<sup>3+</sup> nanostructures demonstrated dominant green emission at 545&#xa0;nm. When excited at 1550&#xa0;nm, the nanostructures exhibit dominant red emission at 667&#xa0;nm. Under 980&#xa0;nm excitation, the Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub>:Er<sup>3+</sup>/Ho<sup>3+</sup> nanostructures exhibit a tunable emission from green to yellow to red by varying the ratio of Er<sup>3+</sup> to Ho<sup>3+</sup>. These results indicate their potential applications in multi-mode anti-counterfeiting and information encryption. In addition, the temperature sensing properties of the Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub>:Er<sup>3+</sup>/Ho<sup>3+</sup> nanostructures are also investigated. The maximum values of <i>S</i><sub><i>a</i></sub> and <i>S</i><sub><i>r</i></sub> are 0.59&#xa0;K<sup>− 1</sup> and 0.94&#xa0;K<sup>− 1</sup> at 303&#xa0;K for Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub>:0.02Er<sup>3+</sup>/0.05Ho<sup>3+</sup>, which are higher than those reported for other phosphors.</p>

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One-dimensional Y2Zr2O7: Er/Ho nanofibers with tunable emission, along with their temperature sensing properties and anti-counterfeiting applications

  • Chenguang Hao,
  • Yuefeng Gao,
  • Hongquan Yu,
  • Sai Xu,
  • Baojiu Chen,
  • LiHong Cheng,
  • Xiaoguang Xu

摘要

One-dimensional Y2Zr2O7:Er3+/Ho3+ nanostructures have been successfully synthesized via a conventional electrospinning technique. Their diameters are in the range of 200–300 nm. The Y2Zr2O7:Er3+/Ho3+ nanostructures exhibit variable emissions under different excitation wavelengths. Under 377 nm excitation, the Y2Zr2O7: Er3+/Ho3+ nanostructures demonstrated dominant green emission at 545 nm. When excited at 1550 nm, the nanostructures exhibit dominant red emission at 667 nm. Under 980 nm excitation, the Y2Zr2O7:Er3+/Ho3+ nanostructures exhibit a tunable emission from green to yellow to red by varying the ratio of Er3+ to Ho3+. These results indicate their potential applications in multi-mode anti-counterfeiting and information encryption. In addition, the temperature sensing properties of the Y2Zr2O7:Er3+/Ho3+ nanostructures are also investigated. The maximum values of Sa and Sr are 0.59 K− 1 and 0.94 K− 1 at 303 K for Y2Zr2O7:0.02Er3+/0.05Ho3+, which are higher than those reported for other phosphors.