Efficient separation of rare earths-bearing monazite from zircon via combined magnetic separation and flotation using sodium N-Lauroylsarcosinate (SNLS) as a promising collector
摘要
Rare earth elements (REEs) are essential to various high-tech applications, including electronics, renewable energy technologies, and advanced defense systems. However, sustainability and efficiently recovering REEs from low-grade ores remain a significant challenge. This study focuses on the efficient separation of monazite, a REEs-bearing mineral, from zircon, utilizing magnetic separation and flotation techniques. Monazite, a paramagnetic mineral, was identified in notable concentration (1.22% REOs) within a feed zircon-rich sample containing 57.90% ZrO2. The magnetic separation was performed using Carpco induced roll magnetic separator, resulting in a paramagnetic monazite pre-concentrate of 12.50% REOs with a high recovery of 96.82%. Simultaneously, zircon was upgraded in the non-magnetic fraction, achieving a ZrO2 content of 61.04% with a recovery exceeding 95%. The monazite rich-fraction was further processed through flotation, employing sodium N-Lauroylsarcosinate (SNLS) as a novel collector and compared to oleic acid. Optimized flotation conditions with SNLS produced a monazite-rich concentrate containing 33.06% REOs and a recovery of 75.16%. Many analytical techniques, including XRD, XRF, FTIR, ICP-OES, SEM, EDS, and photomicrograph were utilized to evaluate the separation efficiency. This work demonstrates the potential of SNLS as a novel collector, presenting a promising pathway for enhancing REEs recovery.