<p>Contamination of food with heavy metal ions and nitrites poses a serious threat to human health. Consequently, the development of fast and sensitive platforms for detecting these contaminants is urgently required. In this paper, a novel MnMgFe-LDHs/DC sensor is constructed based on a simple strategy, in which MnMgFe layered double hydroxide (LDHs) is used as a metal precursor, and a unique "island bridge" carbon network structure is generated by its pyrolysis with ZIF-8@B, N-WMCNTs. The electrical conductivity was enhanced, and a large electroactive surface area was provided for the MnMgFe-LDHs/DC. The electrochemical properties of Pb<sup>2+</sup>, Cd<sup>2+</sup> and nitrite were investigated using this electrode as a working electrode. Under optimized conditions, the sensing platform exhibited a wide linear range with the Pb<sup>2+</sup>, Cd<sup>2+</sup>, and NO<sub>2</sub><sup>−</sup> limits of detection of 46.16&#xa0;nM, 59.25&#xa0;nM, and 0.083&#xa0;μM, respectively. Of particular note is that this sensing platform exhibits outstanding anti-interference capabilities. It can precisely and efficiently conduct the detection of nitrite and heavy metal ions in pickled foods.</p>

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MnMgFe-LDHs/ZIF-8/B, N-WMCNTs nanocomposites for efficient electrochemical detection of nitrite and heavy metal ions

  • Xue Du,
  • Tong Han,
  • Biao Jin,
  • Long-Yue Meng,
  • Lian-Hua Han

摘要

Contamination of food with heavy metal ions and nitrites poses a serious threat to human health. Consequently, the development of fast and sensitive platforms for detecting these contaminants is urgently required. In this paper, a novel MnMgFe-LDHs/DC sensor is constructed based on a simple strategy, in which MnMgFe layered double hydroxide (LDHs) is used as a metal precursor, and a unique "island bridge" carbon network structure is generated by its pyrolysis with ZIF-8@B, N-WMCNTs. The electrical conductivity was enhanced, and a large electroactive surface area was provided for the MnMgFe-LDHs/DC. The electrochemical properties of Pb2+, Cd2+ and nitrite were investigated using this electrode as a working electrode. Under optimized conditions, the sensing platform exhibited a wide linear range with the Pb2+, Cd2+, and NO2 limits of detection of 46.16 nM, 59.25 nM, and 0.083 μM, respectively. Of particular note is that this sensing platform exhibits outstanding anti-interference capabilities. It can precisely and efficiently conduct the detection of nitrite and heavy metal ions in pickled foods.