Understanding the Phosphorus Dynamics in an Acid Alfisol Through Structural Equation Modelling
摘要
Phosphorus (P) is essential for plant growth, but its fixation and transformation into less accessible forms limits its availability to the plant. The pathways of P transformation, underlying controlling factors and their effective management present a critical knowledge gap that needs to be addressed. So, this study was undertaken to gain insights into the P dynamics in an acid Alfisol of north-western Himalayan region. The study utilized a 50-year-old long-term fertilizer experiment comprising eleven fertilization regimes. Sequential fractionation, redundancy analysis, and structural equation modelling were employed to highlight significant alterations in soil P fractions under different treatments. Non-labile P was the predominant pool (51.2%), followed by moderately-labile (34.8%) and labile (14.0%) pools. The phosphorus activity coefficient (PAC), maize yield, and P uptake were maximum under 100% NPK + FYM (farmyard manure) and 100% NPK + lime, with significant improvements over 100% NPK alone. In contrast, continuous P omission resulted in a substantial depletion of total soil P. Pearson’s correlation and redundancy analysis revealed strong positive associations between P fractions, soil organic carbon (SOC), and nutrient availability. Labile and moderately-labile P pools exhibited strong positive correlations with maize yield and P uptake. Structural equation modelling further identified labile P as the primary contributor to available P, while available nitrogen emerged as a key driver of P transformation. In conclusion, the application of FYM and lime, alongside balanced fertilization, is crucial for optimizing P dynamics and for improving and sustaining the agricultural productivity of acidic soils.