Hydrogen-Enriched Combustion of Chicken Skin Waste Biodiesel in Diesel Engines: Performance and Emission Characteristics
摘要
This investigation conducts an experimental analysis of the performance and emission characteristics of biodiesel derived from chicken skin waste (CSW) when combined with hydrogen fumigation in a diesel engine. The CSW, procured from local poultry suppliers, underwent rendering to extract oil, achieving a yield of approximately 35%, which was subsequently subjected to transesterification employing methanol at a molar ratio of 6:1 and a NaOH catalyst at a concentration of 1 wt% at a temperature of 60 °C for 90 min. The biodiesel produced conformed to ASTM D6751 standards, demonstrating a density of 0.873 g/cm³, a kinematic viscosity of 4.7 cSt at 40 °C, a cetane number of 56, and a flash point of 162 °C. Two blends, B20 and B40, were formulated and evaluated in a single-cylinder, four-stroke, water-cooled diesel engine under full load conditions at an operational speed of 1500 rpm. Hydrogen was administered at controlled flow rates of 2 L/min and 4 L/min into the intake manifold to facilitate dual-fuel operation. Performance metrics indicated that the B20 + H₂ (4 L/min) configuration attained the highest brake thermal efficiency (BTE) of 32.1%, in contrast to 30.4% for conventional diesel. Specific fuel consumption (SFC) exhibited a reduction to 0.27 kg/kWh compared to 0.30 kg/kWh for diesel, signifying enhanced combustion efficiency. Emission analysis revealed substantial reductions: carbon monoxide (CO) emissions decreased by 50% (from 420 ppm to 210 ppm), hydrocarbon (HC) emissions diminished by 43% (from 58 ppm to 33 ppm), and smoke opacity reduced by 47% (from 34 to 18%). Nevertheless, nitrogen oxide (NOx) emissions experienced an increase of 17.3%, rising from 980 ppm to 1150 ppm, attributable to elevated in-cylinder temperatures associated with hydrogen combustion. These findings elucidate that the amalgamation of CSB with hydrogen fumigation presents a promising dual-fuel strategy, enhancing engine efficiency while markedly decreasing carbon-based emissions. This methodology offers a sustainable and economically viable solution, particularly advantageous for decentralized and rural energy applications where poultry waste is in surplus.