<p>Formation and evolution of inclusions in low-aluminum Ti-containing 51CrV4 spring steel under BOF (basic oxygen furnace)–LF (ladle furnace)–CC (continuous casting) process were investigated by industrial trials and thermodynamic calculations. During LF refining, deoxidation products including Al<sub>2</sub>O<sub>3</sub>, Al<sub>2</sub>O<sub>3</sub>–Ti<sub>3</sub>O<sub>5</sub>–SiO<sub>2</sub>–MnO and Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub>–MnO are modified as MgO–Al<sub>2</sub>O<sub>3</sub>, CaO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub>, CaO–Al<sub>2</sub>O<sub>3</sub>–MgO and CaO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub>–MgO. When reoxidation during ladle casting is quite serious, inclusions such as Al<sub>2</sub>O<sub>3</sub>, Al<sub>2</sub>O<sub>3</sub>–Ti<sub>3</sub>O<sub>5</sub>–SiO<sub>2</sub>–MnO, and Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub>–MnO may regenerate. A handful of Ti carried by alloy into liquid steel has less influence on inclusions during LF refining; Ti-containing inclusions mainly transiently exist as an intermediate product of deoxidation process and then are gradually modified by [Al], [Ca] or [Mg]. Thermodynamic calculation and experimental results reveal that tundish flux is the main source of reoxidation in ladle casting process. Further calculations taking into account of the influence of inclusions before casting indicate that reoxidation within a certain of degree leads to the generation of a large amount of high melting point inclusions including CaO·2MgO·8Al<sub>2</sub>O<sub>3</sub>, CaO·MgO·7Al<sub>2</sub>O<sub>3</sub>, MgO·Al<sub>2</sub>O<sub>3</sub>, CaO·6Al<sub>2</sub>O<sub>3</sub> and Al<sub>2</sub>O<sub>3</sub> in molten steel, which is basically consistent with experimental results, and more high melting point inclusions will generate as reoxidation becomes severer. On this basis, severer reoxidation will deplete [Si], [Mn], and [Ti] in steel melt, resulting in the formation of liquid inclusions composed of Al<sub>2</sub>O<sub>3</sub>–Ti<sub>3</sub>O<sub>5</sub>–SiO<sub>2</sub>–MnO(–CaO). These results are of guiding significance for controlling inclusions in Al-killed Ti-containing spring steel.</p>

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Formation and evolution of inclusions in low-aluminum Ti-containing 51CrV4 spring steel during BOF–LF–CC process: origin and influence of reoxidation

  • Wei-shuo Tong,
  • Jing Li,
  • Bao-an Mu,
  • Mao-fan Yun

摘要

Formation and evolution of inclusions in low-aluminum Ti-containing 51CrV4 spring steel under BOF (basic oxygen furnace)–LF (ladle furnace)–CC (continuous casting) process were investigated by industrial trials and thermodynamic calculations. During LF refining, deoxidation products including Al2O3, Al2O3–Ti3O5–SiO2–MnO and Al2O3–SiO2–MnO are modified as MgO–Al2O3, CaO–Al2O3–SiO2, CaO–Al2O3–MgO and CaO–Al2O3–SiO2–MgO. When reoxidation during ladle casting is quite serious, inclusions such as Al2O3, Al2O3–Ti3O5–SiO2–MnO, and Al2O3–SiO2–MnO may regenerate. A handful of Ti carried by alloy into liquid steel has less influence on inclusions during LF refining; Ti-containing inclusions mainly transiently exist as an intermediate product of deoxidation process and then are gradually modified by [Al], [Ca] or [Mg]. Thermodynamic calculation and experimental results reveal that tundish flux is the main source of reoxidation in ladle casting process. Further calculations taking into account of the influence of inclusions before casting indicate that reoxidation within a certain of degree leads to the generation of a large amount of high melting point inclusions including CaO·2MgO·8Al2O3, CaO·MgO·7Al2O3, MgO·Al2O3, CaO·6Al2O3 and Al2O3 in molten steel, which is basically consistent with experimental results, and more high melting point inclusions will generate as reoxidation becomes severer. On this basis, severer reoxidation will deplete [Si], [Mn], and [Ti] in steel melt, resulting in the formation of liquid inclusions composed of Al2O3–Ti3O5–SiO2–MnO(–CaO). These results are of guiding significance for controlling inclusions in Al-killed Ti-containing spring steel.