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<p>Aramid nanofiber (ANF) aerogels possess excellent flexibility and favorable mechanical properties. However, their limited infrared transmittance, relatively high thermal conductivity, and low flame retardancy significantly restrict their application in passive thermal management. In this study, a microphase separation strategy is employed to fabricate ANF@Al<sub>2</sub>O<sub>3</sub> composite aerogels, enabling a structural transition from a uniform-pore to a slit-pore morphology. Benefiting from the light regulation by the slit pore structure and the flame-retardant effect of Al<sub>2</sub>O<sub>3</sub>, the prepared ANF@Al<sub>2</sub>O<sub>3</sub> aerogels material have ultra-low thermal conductivity (as low as 30 mW/(m·K)), high infrared transmittance (near-infrared transmittance &gt; 90%), and excellent fire resistance (enhanced combustion endurance), which is able to meet the various needs of passive heating in intelligent buildings. Under outdoor solar irradiation (29.3&#xa0;°C, 677.6&#xa0;W/m<sup>2</sup>), the ANF@Al<sub>2</sub>O<sub>3</sub> composite aerogel achieves an internal temperature of 50.46&#xa0;°C, achieving a relative heating enhancement of 72.22%. This study provides a strategy for designing high-performance composite aramid aerogels and holds great promise for mild thermal insulation applications with potential relevance to aerospace, energy-efficient buildings, and smart thermal management systems.</p> Graphical Abstract <p></p>

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Aramid nanofiber@Al2O3 composite aerogels toward ultra-High near infrared transmittance and low thermal conductivity for robust passive thermal managements

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年12月2日

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  • Yanan Chen,
  • Sijia Ge,
  • Hong Li,
  • Ling Liu,
  • Xueyan Hu,
  • Peiying Hu,
  • Xiaodong Wu,
  • Sheng Cui,
  • Jin Wang

摘要

Aramid nanofiber (ANF) aerogels possess excellent flexibility and favorable mechanical properties. However, their limited infrared transmittance, relatively high thermal conductivity, and low flame retardancy significantly restrict their application in passive thermal management. In this study, a microphase separation strategy is employed to fabricate ANF@Al2O3 composite aerogels, enabling a structural transition from a uniform-pore to a slit-pore morphology. Benefiting from the light regulation by the slit pore structure and the flame-retardant effect of Al2O3, the prepared ANF@Al2O3 aerogels material have ultra-low thermal conductivity (as low as 30 mW/(m·K)), high infrared transmittance (near-infrared transmittance > 90%), and excellent fire resistance (enhanced combustion endurance), which is able to meet the various needs of passive heating in intelligent buildings. Under outdoor solar irradiation (29.3 °C, 677.6 W/m2), the ANF@Al2O3 composite aerogel achieves an internal temperature of 50.46 °C, achieving a relative heating enhancement of 72.22%. This study provides a strategy for designing high-performance composite aramid aerogels and holds great promise for mild thermal insulation applications with potential relevance to aerospace, energy-efficient buildings, and smart thermal management systems.

Graphical Abstract