Thermal behavior, density enhancement, morphological characterization, and theoretical gamma-ray attenuation assessment of TiO2-modified barite concrete
摘要
This study investigates the effect of titanium dioxide (TiO2) incorporation on the density, thermal stability, and gamma-ray shielding performance of barite concrete. Four composites were prepared by partially replacing silica sand with TiO2 (0.0–1.5 g). The bulk density increased from 3.28 to 3.45 g/cm³, indicating improved particle packing. Linear attenuation coefficients (LACs) at 0.015 MeV increased significantly from 89.034 to 104.280 cm⁻¹ with increasing TiO2 content, confirming enhanced photon attenuation. Thermal analyses revealed reduced mass loss in modified samples, with minimum degradation (83%) observed in 1.0 and 1.5 g TiO2 mixes compared to 99% for the control. Differential thermal analysis indicated phase transitions between 210 and 240 °C. Overall, TiO2 addition improved density-driven shielding efficiency while maintaining acceptable thermal performance.