Synthesis and Application of Polystyrene/Sulfonated Bentonite Nanocomposite for Efficient Adsorptive Removal of Toxic Heavy Metals from Wastewater Solutions
摘要
The presence of toxic heavy metals such as cadmium and lead in wastewater poses a serious environmental and health risk due to their persistence and bioaccumulation. In this study, a novel polystyrene/sulfonated bentonite nanocomposite (PS/NSB) was synthesized from low-cost materials and applied as an efficient adsorbent for Cd(II) and Pb(II) removal from aqueous solutions. Structural and morphological characterizations (TEM, FTIR, TGA, SEM, and EDX) confirmed successful functionalization and enhanced surface area. Batch adsorption experiments demonstrated high uptake capacities (200 mg/g for Cd(II) and 135.13 mg/g for Pb(II)), with kinetics following the pseudo-second-order model and equilibrium fitting the Langmuir isotherm, indicating monolayer chemisorption. The nanocomposite exhibited good regeneration over successive cycles, underscoring its reusability. After treatment, residual concentrations of Cd(II) and Pb(II) were reduced to below 0.01 mg/L, meeting WHO/FAO discharge standards. These findings highlight the novelty and practical potential of PS/NSB as a cost-effective and sustainable material for wastewater treatment.
Graphical Abstract