The particle-hole nuclei \(^{134-136}\) Xe are studied using large-scale shell-model calculations with an extended pairing-plus-multipole interaction and monopole corrections. The negative-parity states \(2^{-}\) to \(8^{-}\) in \(^{136}\) Xe are predicted at 3.4–3.9 MeV. The quantitative analysis reveals that the monopole effects provide the dominant contribution to reproducing the spectroscopic structure of \(^{135}\) Xe. The monopole effects between the \(\pi g_{7/2}\) and \(\nu h_{11/2}\) orbits substantially improve the shell-model precision in these particle-hole nuclei \(^{134-136}\) Xe near the doubly magic nucleus \(^{132}\) Sn.