Radiological survey and environmental risk assessment around the fertilizer and phosphoric acid former plant of Sfax, Tunisia
摘要
The phosphate industry along the Sfax coast has significantly altered the surrounding environment through the accumulation of mineral processing by-products, affecting both terrestrial and marine ecosystems. This study assesses radiological conditions at a former phosphate industrial site using in situ measurements acquired with a portable gamma-ray spectrometer. Surveys were conducted across the phosphogypsum (PG) pile, adjacent soils, and nearby beach sediments, focusing on total count rate (TC), absorbed dose rate (DR), and activity concentrations of ²³⁸U and ²³²Th progenies and ⁴⁰K. Two radiological hotspot zones were identified within the PG pile, where TC and DR values reached up to 300 cps and 246 nGy h⁻¹, respectively, with all radiological parameters exceeding recommended reference levels. In surrounding soils, a localized hotspot was detected near the PG pile, while average values in other areas (≈ 30 cps and 45 nGy h⁻¹) remained within permissible limits. Beach sediments exhibited the lowest radioactivity levels (mean TC ≈ 10 cps; DR ≈ 29 nGy h⁻¹), well below thresholds of radiological concern. Statistical analyses indicate that radiation in the PG pile and soils is dominated by ²³⁸U progeny, whereas both ²³⁸U progeny and ⁴⁰K contribute to radioactivity in coastal sediments. From a radiological protection perspective, elevated dose rates measured over the PG pile and nearby soils may lead to annual effective doses approaching or exceeding the public exposure reference level of 1 mSv y⁻¹. This study provides essential baseline radiometric data to support the management of radiological risks in the Sfax coastal industrial zone.