Sustainable Continuous Electrocoagulation of Laboratory Effluents: Optimization, Sludge Characterization, and Circular Economy
摘要
This study demonstrates the treatment of real laboratory effluents using a continuous-flow electrocoagulation (EC) reactor with aluminum electrodes. Under optimized conditions (pH 5.0, conductivity 6.89 mS/cm, current density 10 mA/cm², flow rate 0.1 L/min, HRT 120 min), removal efficiencies reached 83% for COD, 82% for color, 83% for TDS, and 83% for TOC. The process generated 1.3 kg/m³ of sludge, characterized by amorphous aluminum hydroxides (SEM-EDX, XRD, FTIR). Energy consumption was 2.45 kWh/m³, with an operating cost of 0.48 USD/m³. The sludge shows potential for valorization as an adsorbent or construction material, supporting circular economy. The study aligns with SDG 6, SDG 9, and SDG 12.