Effectiveness of CNSL as an admixture for corrosion mitigation and strength development in concrete under simulated marine conditions
摘要
The durability of reinforced concrete structures in marine environments is significantly compromised by chloride-induced corrosion of steel. Chemical corrosion inhibitors are extensively utilized; nonetheless, their environmental effects and cost raise sustainability issues. This study compares the efficiency of a commercial chemical inhibitor (CCI) with cashew nutshell liquid (CNSL), a renewable plant-based byproduct, as a green corrosion inhibitor when added to concrete. This research is innovative as it incorporates CNSL directly into the concrete matrix, rather than applying it as a surface treatment, and uses the maturity index method to estimate strength in real time through IoT-enabled temperature monitoring. Accelerated corrosion tests under simulated marine conditions were performed at 5 V DC to assess corrosion rates over 30, 60, and 120 days. Gravimetric analysis, SEM-BSE/EDAX, and FTIR spectroscopy were employed to evaluate corrosion inhibition and microstructural development. The findings demonstrate that a 0.4% CNSL dosage attained a corrosion inhibition efficiency of 98%, exhibiting enhanced hydration properties, workability, and long-term compressive strength (44.60 MPa) compared to higher CCI dosages. The results confirm CNSL's feasibility as a cost-efficient, environmentally friendly, and technically strong substitute for conventional inhibitors in marine-exposed reinforced concrete structures.