For a rational number a/N with \(1 \le a < N\) , we call the value of the digamma function, \(\psi (a/N)\) , an N-division value. An N-division value is said to be primitive if in addition, \((a,N)=1\) . In this paper, we derive an explicit expression for an N-division value as a rational linear combination of primitive N-division values and logarithms of primes that divide N. For a periodic arithmetic function f, let \(L(s,f) = \sum _{n\ge 1} f(n)\, n^{-s}\) . Due to the connection between division values of the digamma function and L(1, f), our approach leads to new observations regarding the latter.