<p>In-situ TiC and ex-situ SiC reinforced Ni-based composite coatings were fabricated on high-chromium cast iron by laser cladding. The microstructure and properties of the cladding layer were characterized by X-ray diffraction (XRD), optical microscopy (OM), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), microhardness, wear and electrochemical polarization tests. The amount of in-situ generated TiC particles increased with increasing (Ti + SiC) addition. Meanwhile, the microstructure of the coating exhibited grain refinement initially and then coarsening. The coatings with different (Ti + SiC) additions exhibited similar phase compositions, predominantly comprising <i>γ</i>-(Fe, Ni) solid solution, FeNi<sub>3</sub>, CrSi<sub>2</sub>, and carbides such as M<sub>7</sub>C<sub>3</sub>, M<sub>23</sub>C<sub>6</sub>, TiC and residual SiC. At (Ti + SiC) addition of 50&#xa0;wt.%, the <i>γ</i>-(Fe, Ni) solid solution and FeNi<sub>3</sub> phase were completely replaced by <i>α</i>-(Fe, Ni) solid solution and Ni-Cr-Fe phase. After the addition of (Ti + SiC), the hardness and wear resistance of the coatings increased due to the combined strengthening effect of the newly formed TiC and retained SiC particles. With the increase of (Ti + SiC) addition, the corrosion resistance of the coating increased first and then decreased, and the corrosion resistance reached the optimum at a (Ti + SiC) addition of 30&#xa0;wt.%.</p>

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Microstructure, Wear and Corrosion Properties of In-Situ TiC and Ex-Situ SiC Reinforced Ni-Based Laser Cladding Coatings on KmTbCr15Mo High-Chromium Cast Iron

  • Junjie Zhao,
  • Xueshan Du,
  • Zhan Zhang,
  • Zhuoran Li,
  • Chaoyue Wei,
  • Yufu Sun

摘要

In-situ TiC and ex-situ SiC reinforced Ni-based composite coatings were fabricated on high-chromium cast iron by laser cladding. The microstructure and properties of the cladding layer were characterized by X-ray diffraction (XRD), optical microscopy (OM), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), microhardness, wear and electrochemical polarization tests. The amount of in-situ generated TiC particles increased with increasing (Ti + SiC) addition. Meanwhile, the microstructure of the coating exhibited grain refinement initially and then coarsening. The coatings with different (Ti + SiC) additions exhibited similar phase compositions, predominantly comprising γ-(Fe, Ni) solid solution, FeNi3, CrSi2, and carbides such as M7C3, M23C6, TiC and residual SiC. At (Ti + SiC) addition of 50 wt.%, the γ-(Fe, Ni) solid solution and FeNi3 phase were completely replaced by α-(Fe, Ni) solid solution and Ni-Cr-Fe phase. After the addition of (Ti + SiC), the hardness and wear resistance of the coatings increased due to the combined strengthening effect of the newly formed TiC and retained SiC particles. With the increase of (Ti + SiC) addition, the corrosion resistance of the coating increased first and then decreased, and the corrosion resistance reached the optimum at a (Ti + SiC) addition of 30 wt.%.