Silica Fume in Non-Occupying Coatings: Mechanisms and Performance Optimization
摘要
Non-occupying coatings (NOCs) technology employs a “coating-first, molding-second” process, where a curable coating is applied to a pattern and transferred upon demolding to form the mold/core surface, enabling precise geometry replication and defect elimination. This demands superior coating properties, including stability, rheology, and bond strength. Silica fume—an ultrafine powder with high specific surface area and silanol groups—is a promising yet poorly understood reinforcement for NOCs. This study demonstrates that silica fume acts through a triple mechanism: rheological control, structural densification, and interfacial reinforcement. At 3 wt%, it increases brushing index by 66.7% with full suspensibility; at 2 wt%, it reduces liquid carrier demand by 11.8%, halves drying time, and enhances thermal stability. Wear resistance improves by 50.6% via densification, while a synergistic hydrogen–chemical bonding mechanism boosts coating–sand bond strength by 130% (to 182 kPa). These insights guide the design of high-performance NOCs.