<p>The high organic composition of peat poses significant geotechnical challenges, including low shear strength, a highly compressible nature, and substantial creep rates. However, geopolymer, a nontraditional material, offers a promising solution for stabilizing peat, increasing strength, and reducing carbon dioxide (CO<sub>2</sub>) emissions. This study explores the application of fly ash-based geopolymer (FAGP) as a stabilization agent for peat, which exhibits highly variable organic content (17–72%) and fiber content (5–69%). The geopolymer was prepared using sodium hydroxide and fly ash (FA) at varying molarity (M), alkali/binder (L/S) ratios, and binder dosages. The results show that peat stabilization is influenced by various factors such as organic content (OC), binder dosage, activator concentration, L/S ratio, pH, and curing period. Optimal combinations were identified as 20% binder dosage, 12&#xa0;M activator concentration, and 0.7&#xa0;L/S ratio, yielding significant improvements in unconfined compressive strength (UCS)—184, 225, and 167 times higher than untreated hemic (7.18&#xa0;kPa), fibric (8.35&#xa0;kPa), and sapric (12.53&#xa0;kPa) peat, respectively. Additionally, UCS decreased with increasing organic content and increased with the curing period. Further, X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) analysis confirmed the successful synthesis of cementitious materials, including zeolite, which filled pore spaces, supporting the proposed reaction mechanism.</p>

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Fly Ash-Based Geopolymer Stabilized Peat: Experimental Investigation

  • Vishal Raghuwanshi,
  • Monowar Hussain

摘要

The high organic composition of peat poses significant geotechnical challenges, including low shear strength, a highly compressible nature, and substantial creep rates. However, geopolymer, a nontraditional material, offers a promising solution for stabilizing peat, increasing strength, and reducing carbon dioxide (CO2) emissions. This study explores the application of fly ash-based geopolymer (FAGP) as a stabilization agent for peat, which exhibits highly variable organic content (17–72%) and fiber content (5–69%). The geopolymer was prepared using sodium hydroxide and fly ash (FA) at varying molarity (M), alkali/binder (L/S) ratios, and binder dosages. The results show that peat stabilization is influenced by various factors such as organic content (OC), binder dosage, activator concentration, L/S ratio, pH, and curing period. Optimal combinations were identified as 20% binder dosage, 12 M activator concentration, and 0.7 L/S ratio, yielding significant improvements in unconfined compressive strength (UCS)—184, 225, and 167 times higher than untreated hemic (7.18 kPa), fibric (8.35 kPa), and sapric (12.53 kPa) peat, respectively. Additionally, UCS decreased with increasing organic content and increased with the curing period. Further, X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) analysis confirmed the successful synthesis of cementitious materials, including zeolite, which filled pore spaces, supporting the proposed reaction mechanism.