<p>Organic-inorganic hybrid metal halides (OIMHs) based on Cu(I) ions show broad application prospects in the field of stimulus-responsive luminescent materials based on their rich structural diversity and highly adjustable electronic state. However, achieving sensitive and broad-temperature-range thermal responses for OIMHs remains a significant challenge, despite the growing interest in smart luminescence materials. In this study, 4-morpholinopiperidine (4-MP) and CuI are used to synthesize a zero-dimensional warm white-light emitting OIMH, namely MPC-W ((C₉H₂₀N₂O)₄(Cu₂I₄)(Cu₂I₆)(H₂PO₂)₂), which features hybrid structures of [Cu₂I₄]²⁻ and [Cu₂I₆]⁴⁻. Owing to the coexistence of three luminescent mechanisms-organic cluster luminescence (CL), self-trapped exciton (STE) emission of [Cu₂I₆]⁴⁻, and cluster-centered (CC) state luminescence of [Cu₂I₄]²⁻, MPC-W exhibits temperature and excitation wavelength-dependent dynamic luminescence. When the temperature is increased from 77 to 297 K, the luminescence color of MPC-W can be continuously tuned from blue to cyan, green, yellow-green, and white. In the range of 217–463 K, MPC-W displays an abnormal luminescence enhancement phenomenon with increasing temperature. Additionally, upon chemical stimulus, MPC-W can reversibly transform into a blue-light emitting crystal named MPC-B ((C₉H₂₀N₂O)Cu₂I₄), and a yellow-light emitting crystal named MPC-Y ((C₉H₁₈N₂O)₇Cu₈I₈). These unique dynamic luminescent properties endow MPC-W with great application potential in temperature sensing, optical anti-counterfeiting, and password locks. The work provides a new insight for the development of novel wide temperature-responsive multifunctional intelligent luminescent materials.</p>