For \(k\in \mathbb {N}_{0}=\mathbb {N}\cup \{0\}\) and \(x\in (0,1)\) , let \(F(a,b;a+b+k;x)\) and \(Li_{k+1}(x)\) be the k-balanced hypergeometric function and the polylogarithm function, respectively. In this paper, the authors show the monotonicity properties of certain combinations defined in terms of \(F(a,b;a+b+k;x)\) and \(Li_{k+1}(x)\) for a suitable region of (a, b). These results extends the corresponding results of the zero-balanced hypergeometric function for the cases that \(k=0\) , in which cases if we take \(a=b=1/2\) , the results are obtained for the complete complete elliptic integral of the first kind.