<p>This study systematically investigated the effect of CeO<sub>2</sub> addition on the oxidation roasting and subsequent hydrogen reduction behavior of Bayan Obo pellets. A combination of FactSage thermodynamic calculation, isothermal reduction experiments, XRD, and SEM–EDS analysis was employed to evaluate the influence of CeO<sub>2</sub> on the compressive strength, reduction degree, swelling index, microstructure, and elemental distribution of the pellets. Thermodynamic calculations indicated that CeO<sub>2</sub> remained chemically inert and did not react with the iron-containing or slag phases during both oxidation and reduction processes. The compressive strength of the pellets was significantly influenced by the CeO<sub>2</sub> content, initially increasing from 3016 N/P to 3534 N/P at 0.5 wt% CeO<sub>2</sub>, and then decreasing to 2785 N/P at 2.0 wt% addition. At lower reduction temperatures of 600 ℃ and 700 ℃, the incorporation of CeO<sub>2</sub> notably decreased the reduction degree from 44.54 to 33.36% and from 74.05 to 63.68%, respectively. In contrast, at higher temperatures (800 ~ 1000 ℃), CeO<sub>2</sub> had no significant impact on the reduction degree. A critical finding was that CeO<sub>2</sub> addition effectively suppressed reduction swelling, with a pronounced inhibitory effect observed at content between 0.5 wt% and 1.5 wt%. At 1000 ℃, the swelling rate was markedly reduced from 65.05 to 38.12%. However, excessive CeO<sub>2</sub> addition (&gt; 1.5 wt%) disrupted the hematite crystal structure, consequently diminishing pellet strength and the anti-swelling effect.</p> Graphical abstract <p></p>

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Effect of CeO2 on the Oxidation Roasting and Hydrogen Reduction Behavior of Bayan Obo Pellet

  • Qiushi Cui,
  • Fang Zhang,
  • Jun Peng,
  • Yongbin Wang,
  • Fan Yang,
  • Min Li

摘要

This study systematically investigated the effect of CeO2 addition on the oxidation roasting and subsequent hydrogen reduction behavior of Bayan Obo pellets. A combination of FactSage thermodynamic calculation, isothermal reduction experiments, XRD, and SEM–EDS analysis was employed to evaluate the influence of CeO2 on the compressive strength, reduction degree, swelling index, microstructure, and elemental distribution of the pellets. Thermodynamic calculations indicated that CeO2 remained chemically inert and did not react with the iron-containing or slag phases during both oxidation and reduction processes. The compressive strength of the pellets was significantly influenced by the CeO2 content, initially increasing from 3016 N/P to 3534 N/P at 0.5 wt% CeO2, and then decreasing to 2785 N/P at 2.0 wt% addition. At lower reduction temperatures of 600 ℃ and 700 ℃, the incorporation of CeO2 notably decreased the reduction degree from 44.54 to 33.36% and from 74.05 to 63.68%, respectively. In contrast, at higher temperatures (800 ~ 1000 ℃), CeO2 had no significant impact on the reduction degree. A critical finding was that CeO2 addition effectively suppressed reduction swelling, with a pronounced inhibitory effect observed at content between 0.5 wt% and 1.5 wt%. At 1000 ℃, the swelling rate was markedly reduced from 65.05 to 38.12%. However, excessive CeO2 addition (> 1.5 wt%) disrupted the hematite crystal structure, consequently diminishing pellet strength and the anti-swelling effect.

Graphical abstract