<p>V<sub>2</sub>O<sub>5</sub>–TiO<sub>2</sub> selective catalytic reduction (SCR) catalysts represent an effective solution for reducing post-combustion nitrogen oxide (NO<sub>x</sub>) emissions in thermal power plants. This catalyst suffers severe abrasion due to exposure to fly ash. To address this issue, three plate catalyst samples P<sub>1</sub> (Low wt% binder), P<sub>2</sub> (Intermediate wt% binder)<sub>,</sub> and P<sub>3</sub> (High wt% binder) were prepared. A comprehensive analysis of their NO<sub>x</sub> conversion efficiency, air jet abrasion rate, abrasion resistance (sand drop test), and bonding strength (plate drop test) was performed. The better-performing P<sub>2</sub> plate from abrasion tests was chosen for later characterization study. BET, Mercury Porosimetry, XRD, and SEM were used to investigate the morphology, composition, and surface characteristics of the catalyst. Further, the P<sub>2</sub> plates are stacked into a customized air jet abrasion setup where variations in velocity, flow rate, particle diameter, and duration of abrasion, depicting real case scenarios were considered for the experiment. The abrasion rate has followed the abrasion model developed by Iain Finnie. The P<sub>2</sub> Plate samples were chosen for the study of and its effect on De-NO<sub>x</sub> efficiency and were calcined at different temperatures (500◦C, 600◦C and 700◦C), and their De-NO<sub>x</sub> efficiencies at different flue gas temperatures ranging from 300&#xa0;°C—450&#xa0;°C were investigated. This increase in the temperature of flue gases had varied catalyst De-NO<sub>x</sub> efficiencies. The De-NO<sub>x</sub> efficiency, Specific Surface Area, and Pore Volume decrease as the wt% of the binder in the composition increases. The findings propose a protocol for comprehensive characterization of the V<sub>2</sub>O<sub>5</sub>–TiO<sub>2</sub> SCR plate catalyst.</p>

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V2O5-TiO2 SCR Plate Catalysts for High Dust De-NOx Applications: A Comprehensive Characterization Study

  • S. Rajath,
  • Muzammil Bagewadi,
  • N. D. Shivakumar

摘要

V2O5–TiO2 selective catalytic reduction (SCR) catalysts represent an effective solution for reducing post-combustion nitrogen oxide (NOx) emissions in thermal power plants. This catalyst suffers severe abrasion due to exposure to fly ash. To address this issue, three plate catalyst samples P1 (Low wt% binder), P2 (Intermediate wt% binder), and P3 (High wt% binder) were prepared. A comprehensive analysis of their NOx conversion efficiency, air jet abrasion rate, abrasion resistance (sand drop test), and bonding strength (plate drop test) was performed. The better-performing P2 plate from abrasion tests was chosen for later characterization study. BET, Mercury Porosimetry, XRD, and SEM were used to investigate the morphology, composition, and surface characteristics of the catalyst. Further, the P2 plates are stacked into a customized air jet abrasion setup where variations in velocity, flow rate, particle diameter, and duration of abrasion, depicting real case scenarios were considered for the experiment. The abrasion rate has followed the abrasion model developed by Iain Finnie. The P2 Plate samples were chosen for the study of and its effect on De-NOx efficiency and were calcined at different temperatures (500◦C, 600◦C and 700◦C), and their De-NOx efficiencies at different flue gas temperatures ranging from 300 °C—450 °C were investigated. This increase in the temperature of flue gases had varied catalyst De-NOx efficiencies. The De-NOx efficiency, Specific Surface Area, and Pore Volume decrease as the wt% of the binder in the composition increases. The findings propose a protocol for comprehensive characterization of the V2O5–TiO2 SCR plate catalyst.