<p>Sustainable water, energy and food (WEF) supplies are the bedrock upon which human society depends. Solar-driven interfacial evaporation, combined with electricity generation and cultivation, is a promising approach to mitigate the freshwater, energy and food crises. However, the performance of solar-driven systems decreases significantly during operation due to uncontrollable weather. This study proposes an integrated water/electricity cogeneration–cultivation system with superior thermal management. The energy storage evaporator, consisting of energy storage microcapsules/hydrogel composites, is optimally designed for sustainable desalination, achieving an evaporation rate of around 1.91 kg m⁻² h⁻¹. In the dark, heat released from the phase-change layer supported an evaporation rate of around 0.54 kg m⁻² h⁻¹. Reverse electrodialysis harnessed the salinity-gradient energy enhanced during desalination, enabling the long-running WEC system to achieve a power output of ~0.3 W m⁻², which was almost three times higher than that of conventional seawater/surface water mixing. Additionally, an integrated crop irrigation platform utilized system drainage for real-time, on-demand wheat cultivation without secondary contaminants, facilitating seamless WEF integration. This work presents a novel approach to all-day solar water production, electricity generation and crop irrigation, offering a solution and blueprint for the sustainable development of WEF.</p><p></p>