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<p>Finding ways to produce dense and smooth perovskite films with negligible defects is vital for achieving high-efficiency perovskite solar cells (PSCs). Herein, we aim to enhance the quality of the perovskite films through the utilization of a multifunctional additive in the perovskite anti-solvent, a strategy referred to as anti-solvent additive engineering. Specifically, we introduce ortho-substituted-4′-(4,4″-di-tert-butyl-1,1′:3′,1″-terphenyl)-graphdiyne (o-TB-GDY) as an AAE additive, characterized by its <i>sp</i>/<i>sp</i><sup>2</sup>-cohybridized and highly <i>π</i>-conjugated structure, into the anti-solvent. o-TB-GDY not only significantly passivates undercoordinated lead defects (through potent coordination originating from specific high <i>π</i>–electron conjugation), but also serves as nucleation seeds to effectively enhance the nucleation and growth of perovskite crystals. This markedly reduces defects and non-radiative recombination, thereby increasing the power conversion efficiency (PCE) to 25.62% (certified as 25.01%). Meanwhile, the PSCs exhibit largely enhanced stability, maintaining 92.6% of their initial PCEs after 500&#xa0;h continuous 1-sun illumination at ~ 23&#xa0;°C in a nitrogen-filled glove box.</p>

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Multifunctional Graphdiyne Enables Efficient Perovskite Solar Cells via Anti-Solvent Additive Engineering

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年1月28日

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  • Cong Shao,
  • Jingyi He,
  • Jiaxin Ma,
  • Yirong Wang,
  • Guosheng Niu,
  • Pengfei Zhang,
  • Kaiyi Yang,
  • Yao Zhao,
  • Fuyi Wang,
  • Yongjun Li,
  • Jizheng Wang

摘要

Finding ways to produce dense and smooth perovskite films with negligible defects is vital for achieving high-efficiency perovskite solar cells (PSCs). Herein, we aim to enhance the quality of the perovskite films through the utilization of a multifunctional additive in the perovskite anti-solvent, a strategy referred to as anti-solvent additive engineering. Specifically, we introduce ortho-substituted-4′-(4,4″-di-tert-butyl-1,1′:3′,1″-terphenyl)-graphdiyne (o-TB-GDY) as an AAE additive, characterized by its sp/sp2-cohybridized and highly π-conjugated structure, into the anti-solvent. o-TB-GDY not only significantly passivates undercoordinated lead defects (through potent coordination originating from specific high π–electron conjugation), but also serves as nucleation seeds to effectively enhance the nucleation and growth of perovskite crystals. This markedly reduces defects and non-radiative recombination, thereby increasing the power conversion efficiency (PCE) to 25.62% (certified as 25.01%). Meanwhile, the PSCs exhibit largely enhanced stability, maintaining 92.6% of their initial PCEs after 500 h continuous 1-sun illumination at ~ 23 °C in a nitrogen-filled glove box.