Let G be a complex reductive group and \(D\, \subset \, X\) a finite subset of a compact Riemann surface X. It was shown in Biswas and Jeffrey (Ann Math Québec 45: 213–219, 2021) that the moduli space of G–characters of \(\pi _1(X{\setminus } D)\) has a natural Poisson structure. We show that the moduli space of logarithmic G–connections on X singular over D has a Poisson structure. It is proved that the monodromy map from the moduli space of logarithmic G–connections to the moduli space of G–characters is Poisson structure preserving.